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2020

Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex

Fisher, K. J., Feuer, M. L., Lant, H. M. C., Mercado, B. Q., Crabtree, R. H. & Brudvig, G. W., Feb 14 2020, In : Chemical Science. 11, 6, p. 1683-1690 8 p.

Research output: Contribution to journalArticle

Open Access
1 Citation (Scopus)

Cryo-EM Structure of Monomeric Photosystem II from Synechocystis sp. PCC 6803 Lacking the Water-Oxidation Complex

Gisriel, C. J., Zhou, K., Huang, H. L., Debus, R. J., Xiong, Y. & Brudvig, G. W., 2020, (Accepted/In press) In : Joule.

Research output: Contribution to journalArticle

D1-S169A substitution of photosystem II reveals a novel S2-state structure

Ghosh, I., Banerjee, G., Reiss, K., Kim, C. J., Debus, R. J., Batista, V. S. & Brudvig, G. W., Dec 1 2020, In : Biochimica et Biophysica Acta - Bioenergetics. 1861, 12, 148301.

Research output: Contribution to journalArticle

Diazo coupling for surface attachment of small molecules to TiO2 nanoparticles

Troiano, J. L., Hu, G., Crabtree, R. H. & Brudvig, G. W., Aug 13 2020, In : Chemical Communications. 56, 65, p. 9340-9343 4 p.

Research output: Contribution to journalArticle

Heterogeneous Nature of Electrocatalytic CO/CO2 Reduction by Cobalt Phthalocyanines

Wu, Y., Hu, G., Rooney, C. L., Brudvig, G. W. & Wang, H., 2020, (Accepted/In press) In : ChemSusChem.

Research output: Contribution to journalArticle

Identification of a Na+-Binding Site near the Oxygen-Evolving Complex of Spinach Photosystem II

Wang, J., Perez-Cruet, J. M., Huang, H. L., Reiss, K., Gisriel, C. J., Banerjee, G., Kaur, D., Ghosh, I., Dziarski, A., Gunner, M. R., Batista, V. S. & Brudvig, G. W., Aug 4 2020, In : Biochemistry. 59, 30, p. 2823-2831 9 p.

Research output: Contribution to journalArticle

Opportunities and challenges for assigning cofactors in cryo-EM density maps of chlorophyll-containing proteins

Gisriel, C. J., Wang, J., Brudvig, G. W. & Bryant, D. A., Dec 1 2020, In : Communications Biology. 3, 1, 408.

Research output: Contribution to journalArticle

Open Access

Surprisingly big linker-dependence of activity and selectivity in CO2reduction by an iridium(i) pincer complex

Hu, G., Jiang, J. J., Kelly, H. R., Matula, A. J., Wu, Y., Romano, N., Mercado, B. Q., Wang, H., Batista, V. S., Crabtree, R. H. & Brudvig, G. W., Aug 18 2020, In : Chemical Communications. 56, 64, p. 9126-9129 4 p.

Research output: Contribution to journalArticle

Synthesis of organometallic pincer-supported cobalt(II) complexes

Townsend, T. M., Bernskoetter, W. H., Brudvig, G. W., Hazari, N., Lant, H. M. C. & Mercado, B. Q., Feb 1 2020, In : Polyhedron. 177, 114308.

Research output: Contribution to journalArticle

1 Citation (Scopus)
2019

Bicarbonate rescues damaged proton-transfer pathway in photosystem II

Banerjee, G., Ghosh, I., Kim, C. J., Debus, R. J. & Brudvig, G. W., Aug 1 2019, In : Biochimica et Biophysica Acta - Bioenergetics. 1860, 8, p. 611-617 7 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)

Bis(dialkylphosphino)ferrocene-Ligated Nickel(II) Precatalysts for Suzuki-Miyaura Reactions of Aryl Carbonates

Barth, E. L., Davis, R. M., Mohadjer Beromi, M., Walden, A. G., Balcells, D., Brudvig, G. W., Dardir, A. H., Hazari, N., Lant, H. M. C., Mercado, B. Q. & Peczak, I. L., Sep 9 2019, In : Organometallics. 38, 17, p. 3377-3387 11 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)

D1-S169A Substitution of Photosystem II Perturbs Water Oxidation

Ghosh, I., Banerjee, G., Kim, C. J., Reiss, K., Batista, V. S., Debus, R. J. & Brudvig, G. W., Mar 12 2019, In : Biochemistry. 58, 10, p. 1379-1387 9 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies

Charboneau, D. J., Brudvig, G. W., Hazari, N., Lant, H. M. C. & Saydjari, A. K., Apr 5 2019, In : ACS Catalysis. 9, 4, p. 3228-3241 14 p.

Research output: Contribution to journalArticle

24 Citations (Scopus)

Facet-Dependent Kinetics and Energetics of Hematite for Solar Water Oxidation Reactions

Li, W., Yang, K. R., Yao, X., He, Y., Dong, Q., Brudvig, G. W., Batista, V. S. & Wang, D., Feb 13 2019, In : ACS Applied Materials and Interfaces. 11, 6, p. 5616-5622 7 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

Insights into Proton-Transfer Pathways during Water Oxidation in Photosystem II

Ghosh, I., Khan, S., Banerjee, G., Dziarski, A., Vinyard, D. J., Debus, R. J. & Brudvig, G. W., Oct 3 2019, In : Journal of Physical Chemistry B. 123, 39, p. 8195-8202 8 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)
3 Citations (Scopus)

Metal-Organic Framework Photoconductivity via Time-Resolved Terahertz Spectroscopy

Pattengale, B., Neu, J., Ostresh, S., Hu, G., Spies, J. A., Okabe, R., Brudvig, G. W. & Schmuttenmaer, C. A., Jun 26 2019, In : Journal of the American Chemical Society. 141, 25, p. 9793-9797 5 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)

Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds

Shopov, D. Y., Sharninghausen, L. S., Sinha, S. B., Mercado, B. Q., Brudvig, G. W. & Crabtree, R. H., Jan 1 2019, In : Inorganica Chimica Acta. 484, p. 75-78 4 p.

Research output: Contribution to journalArticle

N,N,O Pincer Ligand with a Deprotonatable Site That Promotes Redox-Leveling, High Mn Oxidation States, and a Mn 2 O 2 Dimer Competent for Catalytic Oxygen Evolution

Lant, H. M. C., Michaelos, T. K., Sharninghausen, L. S., Mercado, B. Q., Crabtree, R. H. & Brudvig, G. W., Apr 24 2019, In : European Journal of Inorganic Chemistry. 2019, 15, p. 2115-2123 9 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)

Relative stability of the S2 isomers of the oxygen evolving complex of photosystem II

Kaur, D., Szejgis, W., Mao, J., Amin, M., Reiss, K. M., Askerka, M., Cai, X., Khaniya, U., Zhang, Y., Brudvig, G. W., Batista, V. S. & Gunner, M. R., Sep 1 2019, In : Photosynthesis Research. 141, 3, p. 331-341 11 p.

Research output: Contribution to journalArticle

5 Citations (Scopus)

Silatrane Anchors for Metal Oxide Surfaces: Optimization for Potential Photocatalytic and Electrocatalytic Applications

Materna, K. L., Jiang, J., Crabtree, R. H. & Brudvig, G. W., Feb 13 2019, In : ACS Applied Materials and Interfaces. 11, 6, p. 5602-5609 8 p.

Research output: Contribution to journalArticle

10 Citations (Scopus)

Strongly Coupled Phenazine-Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage

Lee, S. H., Matula, A. J., Hu, G., Troiano, J. L., Karpovich, C. J., Crabtree, R. H., Batista, V. S. & Brudvig, G. W., Feb 27 2019, In : ACS Applied Materials and Interfaces. 11, 8, p. 8000-8008 9 p.

Research output: Contribution to journalArticle

11 Citations (Scopus)

Synthesis and Reactivity of Paramagnetic Nickel Polypyridyl Complexes Relevant to C(sp 2 )–C(sp 3 )Coupling Reactions

Mohadjer Beromi, M., Brudvig, G. W., Hazari, N., Lant, H. M. C. & Mercado, B. Q., Apr 23 2019, In : Angewandte Chemie - International Edition. 58, 18, p. 6094-6098 5 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

Thermodynamics of the S2-To-S3 state transition of the oxygen-evolving complex of photosystem II

Amin, M., Kaur, D., Yang, K. R., Wang, J., Mohamed, Z., Brudvig, G. W., Gunner, M. R. & Batista, V., Jan 1 2019, In : Physical Chemistry Chemical Physics. 21, 37, p. 20840-20848 9 p.

Research output: Contribution to journalArticle

3 Citations (Scopus)
2018

Active sites of copper-complex catalytic materials for electrochemical carbon dioxide reduction

Weng, Z., Wu, Y., Wang, M., Jiang, J., Yang, K., Huo, S., Wang, X. F., Ma, Q., Brudvig, G. W., Batista, V. S., Liang, Y., Feng, Z. & Wang, H., Dec 1 2018, In : Nature communications. 9, 1, 415.

Research output: Contribution to journalArticle

133 Citations (Scopus)

A Dinuclear Iridium(V,V) Oxo-Bridged Complex Characterized Using a Bulk Electrolysis Technique for Crystallizing Highly Oxidizing Compounds

Shopov, D. Y., Sharninghausen, L. S., Sinha, S. B., Mercado, B. Q., Balcells, D., Brudvig, G. W. & Crabtree, R. H., May 7 2018, In : Inorganic Chemistry. 57, 9, p. 5684-5691 8 p.

Research output: Contribution to journalArticle

6 Citations (Scopus)

Direct Interfacial Electron Transfer from High-Potential Porphyrins into Semiconductor Surfaces: A Comparison of Linkers and Anchoring Groups

Jiang, J., Spies, J. A., Swierk, J. R., Matula, A. J., Regan, K. P., Romano, N., Brennan, B. J., Crabtree, R. H., Batista, V. S., Schmuttenmaer, C. A. & Brudvig, G. W., Jun 28 2018, In : Journal of Physical Chemistry C. 122, 25, p. 13529-13539 11 p.

Research output: Contribution to journalArticle

15 Citations (Scopus)

End-On Bound Iridium Dinuclear Heterogeneous Catalysts on WO3 for Solar Water Oxidation

Zhao, Y., Yan, X., Yang, K. R., Cao, S., Dong, Q., Thorne, J. E., Materna, K. L., Zhu, S., Pan, X., Flytzani-Stephanopoulos, M., Brudvig, G. W., Batista, V. S. & Wang, D., Sep 26 2018, In : ACS Central Science. 4, 9, p. 1166-1172 7 p.

Research output: Contribution to journalArticle

24 Citations (Scopus)

Endothelial Cell Autonomous Role of Akt1

Lee, M. Y., Gamez-Mendez, A., Zhang, J., Zhuang, Z., Vinyard, D. J., Kraehling, J., Velazquez, H., Brudvig, G. W., Kyriakides, T. R., Simons, M. & Sessa, W. C., Apr 1 2018, In : Arteriosclerosis, Thrombosis, and Vascular Biology. 38, 4, p. 870-879 10 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)

Highly Active NiO Photocathodes for H2O2 Production Enabled via Outer-Sphere Electron Transfer

Jung, O., Pegis, M. L., Wang, Z., Banerjee, G., Nemes, C. T., Hoffeditz, W. L., Hupp, J. T., Schmuttenmaer, C. A., Brudvig, G. W. & Mayer, J. M., Mar 21 2018, In : Journal of the American Chemical Society. 140, 11, p. 4079-4084 6 p.

Research output: Contribution to journalArticle

21 Citations (Scopus)

Modifications to the Aryl Group of dppf-Ligated Ni σ-Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions

Mohadjer Beromi, M., Banerjee, G., Brudvig, G. W., Charboneau, D. J., Hazari, N., Lant, H. M. C. & Mercado, B. Q., Nov 12 2018, In : Organometallics. 37, 21, p. 3943-3955 13 p.

Research output: Contribution to journalArticle

9 Citations (Scopus)

Nickel(I) Aryl Species: Synthesis, Properties, and Catalytic Activity

Mohadjer Beromi, M., Banerjee, G., Brudvig, G. W., Hazari, N. & Mercado, B. Q., Mar 2 2018, In : ACS Catalysis. 8, 3, p. 2526-2533 8 p.

Research output: Contribution to journalArticle

25 Citations (Scopus)

Oxidation of Organic Compounds in Water by Unactivated Peroxymonosulfate

Yang, Y., Banerjee, G., Brudvig, G. W., Kim, J. H. & Pignatello, J. J., May 15 2018, In : Environmental Science and Technology. 52, 10, p. 5911-5919 9 p.

Research output: Contribution to journalArticle

116 Citations (Scopus)

Reduced Occupancy of the Oxygen-Evolving Complex of Photosystem II Detected in Cryo-Electron Microscopy Maps

Wang, J., Reiss, K., Brudvig, G. W. & Batista, V. S., Oct 16 2018, In : Biochemistry. 57, 41, p. 5925-5929 5 p.

Research output: Contribution to journalArticle

1 Citation (Scopus)

Selective CO Production by Photoelectrochemical Methane Oxidation on TiO2

Li, W., He, D., Hu, G., Li, X., Banerjee, G., Li, J., Lee, S. H., Dong, Q., Gao, T., Brudvig, G. W., Waegele, M. M., Jiang, D. E. & Wang, D., May 23 2018, In : ACS Central Science. 4, 5, p. 631-637 7 p.

Research output: Contribution to journalArticle

12 Citations (Scopus)

Stable iridium dinuclear heterogeneous catalysts supported on metal-oxide substrate for solar water oxidation

Zhao, Y., Yang, K. R., Wang, Z., Yan, X., Cao, S., Ye, Y., Dong, Q., Zhang, X., Thorne, J. E., Jin, L., Materna, K. L., Trimpalis, A., Bai, H., Fakra, S. C., Zhong, X., Wang, P., Pan, X., Guo, J., Flytzani-Stephanopoulos, M., Brudvig, G. W. & 2 others, Batista, V. S. & Wang, D., Mar 20 2018, In : Proceedings of the National Academy of Sciences of the United States of America. 115, 12, p. 2902-2907 6 p.

Research output: Contribution to journalArticle

69 Citations (Scopus)

Substitution of the D1-Asn87 site in photosystem II of cyanobacteria mimics the chloride-binding characteristics of spinach photosystem II

Banerjee, G., Ghosh, I., Kim, C. J., Debus, R. J. & Brudvig, G. W., Feb 16 2018, In : Journal of Biological Chemistry. 293, 7, p. 2487-2497 11 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

Unusual Stability of a Bacteriochlorin Electrocatalyst under Reductive Conditions. A Case Study on CO2 Conversion to CO

Jiang, J., Matula, A. J., Swierk, J. R., Romano, N., Wu, Y., Batista, V. S., Crabtree, R. H., Lindsey, J. S., Wang, H. & Brudvig, G. W., Nov 2 2018, In : ACS Catalysis. 8, 11, p. 10131-10136 6 p.

Research output: Contribution to journalArticle

12 Citations (Scopus)

Water-Nucleophilic Attack Mechanism for the CuII(pyalk)2 Water-Oxidation Catalyst

Rudshteyn, B., Fisher, K. J., Lant, H. M. C., Yang, K. R., Mercado, B. Q., Brudvig, G. W., Crabtree, R. H. & Batista, V. S., Sep 7 2018, In : ACS Catalysis. 8, 9, p. 7952-7960 9 p.

Research output: Contribution to journalArticle

16 Citations (Scopus)
2017

A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

Shopov, D. Y., Rudshteyn, B., Campos, J., Vinyard, D. J., Batista, V. S., Brudvig, G. W. & Crabtree, R. H., 2017, In : Chemical Science. 8, 2, p. 1642-1652 11 p.

Research output: Contribution to journalArticle

19 Citations (Scopus)

Antimony Complexes for Electrocatalysis: Activity of a Main-Group Element in Proton Reduction

Jiang, J., Materna, K. L., Hedström, S., Yang, K. R., Crabtree, R. H., Batista, V. S. & Brudvig, G. W., Jan 1 2017, In : Angewandte Chemie - International Edition. 56, 31, p. 9111-9115 5 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

A pomegranate-structured sulfur cathode material with triple confinement of lithium polysulfides for high-performance lithium-sulfur batteries

Mi, Y., Liu, W., Wang, Q., Jiang, J., Brudvig, G. W., Zhou, H. & Wang, H., 2017, In : Journal of Materials Chemistry A. 5, 23, p. 11788-11793 6 p.

Research output: Contribution to journalArticle

14 Citations (Scopus)

A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis

Michaelos, T. K., Shopov, D. Y., Sinha, S. B., Sharninghausen, L. S., Fisher, K. J., Lant, H. M. C., Crabtree, R. H. & Brudvig, G. W., Apr 18 2017, In : Accounts of Chemical Research. 50, 4, p. 952-959 8 p.

Research output: Contribution to journalArticle

48 Citations (Scopus)

Characterization of ammonia binding to the second coordination shell of the oxygen-evolving complex of photosystem II

Mandal, M., Askerka, M., Banerjee, G., Amin, M., Brudvig, G. W., Batista, V. S. & Gunner, M. R., Jan 1 2017, In : Dalton Transactions. 46, 46, p. 16089-16095 7 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Chlorophyll a with a farnesyl tail in thermophilic cyanobacteria

Wiwczar, J. M., LaFountain, A. M., Wang, J., Frank, H. A. & Brudvig, G. W., Nov 1 2017, In : Photosynthesis Research. 134, 2, p. 175-182 8 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

Crystallographic Data Support the Carousel Mechanism of Water Supply to the Oxygen-Evolving Complex of Photosystem II

Wang, J., Askerka, M., Brudvig, G. W. & Batista, V. S., Oct 13 2017, In : ACS Energy Letters. 2, 10, p. 2299-2306 8 p.

Research output: Contribution to journalArticle

27 Citations (Scopus)

Electrocatalytic Water Oxidation by a Copper(II) Complex of an Oxidation-Resistant Ligand

Fisher, K. J., Materna, K. L., Mercado, B. Q., Crabtree, R. H. & Brudvig, G. W., May 5 2017, In : ACS Catalysis. 7, 5, p. 3384-3387 4 p.

Research output: Contribution to journalArticle

65 Citations (Scopus)

Electroreduction of CO2 Catalyzed by a Heterogenized Zn-Porphyrin Complex with a Redox-Innocent Metal Center

Wu, Y., Jiang, J., Weng, Z., Wang, M., Broere, D. L. J., Zhong, Y., Brudvig, G. W., Feng, Z. & Wang, H., Aug 23 2017, In : ACS Central Science. 3, 8, p. 847-852 6 p.

Research output: Contribution to journalArticle

75 Citations (Scopus)

Energetics of the S2 State Spin Isomers of the Oxygen-Evolving Complex of Photosystem II

Vinyard, D. J., Khan, S., Askerka, M., Batista, V. S. & Brudvig, G. W., Feb 9 2017, In : Journal of Physical Chemistry B. 121, 5, p. 1020-1025 6 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

Linker Length-Dependent Electron-Injection Dynamics of Trimesitylporphyrins on SnO2 Films

Lee, S. H., Regan, K. P., Hedström, S., Matula, A. J., Chaudhuri, S., Crabtree, R. H., Batista, V. S., Schmuttenmaer, C. A. & Brudvig, G. W., Oct 19 2017, In : Journal of Physical Chemistry C. 121, 41, p. 22690-22699 10 p.

Research output: Contribution to journalArticle

5 Citations (Scopus)