• 2398 Citations
  • 29 h-Index
19972020

Research output per year

If you made any changes in Pure these will be visible here soon.

Research Output

2020
Open Access

Unexpected Roles of Triethanolamine in the Photochemical Reduction of CO2 to Formate by Ruthenium Complexes

Sampaio, R. N., Grills, D. C., Polyansky, D. E., Szalda, D. J. & Fujita, E., Feb 5 2020, In : Journal of the American Chemical Society. 142, 5, p. 2413-2428 16 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Vibrational Spectroscopy Reveals Effects of Electron Push-Pull and Solvent Polarity on Electron Delocalization in Radical Anions of Donor-Acceptor Compounds

Boudreau, A. M., Wilson, R. W., Yang, M., Grills, D. C. & Mani, T., Feb 27 2020, In : Journal of Physical Chemistry B. 124, 8, p. 1543-1549 7 p.

Research output: Contribution to journalArticle

2019

An Investigation of Electrocatalytic CO2 Reduction Using a Manganese Tricarbonyl Biquinoline Complex

McKinnon, M., Belkina, V., Ngo, K. T., Ertem, M. Z., Grills, D. C. & Rochford, J., Sep 24 2019, In : Frontiers in Chemistry. 7, 628.

Research output: Contribution to journalArticle

Open Access
1 Citation (Scopus)

Synergistic Metal-Ligand Redox Cooperativity for Electrocatalytic CO 2 Reduction Promoted by a Ligand-Based Redox Couple in Mn and Re Tricarbonyl Complexes

McKinnon, M., Ngo, K. T., Sobottka, S., Sarkar, B., Ertem, M. Z., Grills, D. C. & Rochford, J., Mar 25 2019, In : Organometallics. 38, 6, p. 1317-1329 13 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

Thermodynamic cycles relevant to hydrogenation of CO2 to formic acid in water and acetonitrile

Matsubara, Y., Grills, D. C. & Koide, Y., Jan 1 2019, In : Chemistry Letters. 48, 7, p. 627-629 3 p.

Research output: Contribution to journalArticle

1 Citation (Scopus)
2018

Investigation of excited state, reductive quenching, and intramolecular electron transfer of Ru(II)-Re(i) supramolecular photocatalysts for CO2 reduction using time-resolved IR measurements

Koike, K., Grills, D. C., Tamaki, Y., Fujita, E., Okubo, K., Yamazaki, Y., Saigo, M., Mukuta, T., Onda, K. & Ishitani, O., 2018, In : Chemical Science. 9, 11, p. 2961-2974 14 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)

Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

Grills, D. C., Ertem, M. Z., McKinnon, M., Ngo, K. T. & Rochford, J., Nov 1 2018, In : Coordination Chemistry Reviews. 374, p. 173-217 45 p.

Research output: Contribution to journalReview article

39 Citations (Scopus)
4 Citations (Scopus)

Radiolytic formation of the carbon dioxide radical anion in acetonitrile revealed by transient IR spectroscopy

Grills, D. & Lymar, S. V., Jan 1 2018, In : Physical Chemistry Chemical Physics. 20, 15, p. 10011-10017 7 p.

Research output: Contribution to journalArticle

5 Citations (Scopus)
2017

Application of Pulse Radiolysis to Mechanistic Investigations of Catalysis Relevant to Artificial Photosynthesis

Grills, D. C., Polyansky, D. E. & Fujita, E., Nov 23 2017, In : ChemSusChem. 10, 22, p. 4359-4373 15 p.

Research output: Contribution to journalReview article

14 Citations (Scopus)

Probing Intermolecular Electron Delocalization in Dimer Radical Anions by Vibrational Spectroscopy

Mani, T. & Grills, D., Aug 3 2017, In : Journal of Physical Chemistry B. 121, 30, p. 7327-7335 9 p.

Research output: Contribution to journalArticle

8 Citations (Scopus)

Turning on the Protonation-First Pathway for Electrocatalytic CO2 Reduction by Manganese Bipyridyl Tricarbonyl Complexes

Ngo, K. T., McKinnon, M., Mahanti, B., Narayanan, R., Grills, D. C., Ertem, M. Z. & Rochford, J., Feb 22 2017, In : Journal of the American Chemical Society. 139, 7, p. 2604-2618 15 p.

Research output: Contribution to journalArticle

104 Citations (Scopus)
2016

Electrocatalytic Reduction of Carbon Dioxide with a Well-Defined PN3-Ru Pincer Complex

Min, S., Rasul, S., Li, H., Grills, D. C., Takanabe, K., Li, L. J. & Huang, K. W., Feb 1 2016, In : ChemPlusChem. 81, 2, p. 166-171 6 p.

Research output: Contribution to journalArticle

12 Citations (Scopus)
10 Citations (Scopus)

Identification of Ion-Pair Structures in Solution by Vibrational Stark Effects

Hack, J., Grills, D. C., Miller, J. R. & Mani, T., Feb 18 2016, In : Journal of Physical Chemistry B. 120, 6, p. 1149-1157 9 p.

Research output: Contribution to journalArticle

10 Citations (Scopus)
2015

Development of nanosecond time-resolved infrared detection at the LEAF pulse radiolysis facility

Grills, D. C., Farrington, J. A., Layne, B. H., Preses, J. M., Bernstein, H. J. & Wishart, J. F., Apr 1 2015, In : Review of Scientific Instruments. 86, 4, 044102.

Research output: Contribution to journalArticle

16 Citations (Scopus)

Electron Localization of Anions Probed by Nitrile Vibrations

Mani, T., Grills, D. C., Newton, M. D. & Miller, J. R., Sep 2 2015, In : Journal of the American Chemical Society. 137, 34, p. 10979-10991 13 p.

Research output: Contribution to journalArticle

17 Citations (Scopus)

Thermodynamic Aspects of Electrocatalytic CO2 Reduction in Acetonitrile and with an Ionic Liquid as Solvent or Electrolyte

Matsubara, Y., Grills, D. & Kuwahara, Y., Nov 6 2015, In : ACS Catalysis. 5, 11, p. 6440-6452 13 p.

Research output: Contribution to journalArticle

80 Citations (Scopus)

Vibrational stark effects to identify ion pairing and determine reduction potentials in electrolyte-free environments

Mani, T., Grills, D. C. & Miller, J. R., Jan 28 2015, In : Journal of the American Chemical Society. 137, 3, p. 1136-1140 5 p.

Research output: Contribution to journalArticle

18 Citations (Scopus)
2014

Electrocatalytic CO2 reduction with a homogeneous catalyst in ionic liquid: High catalytic activity at low overpotential

Grills, D. C., Matsubara, Y., Kuwahara, Y., Golisz, S. R., Kurtz, D. A. & Mello, B. A., Jun 5 2014, In : Journal of Physical Chemistry Letters. 5, 11, p. 2033-2038 6 p.

Research output: Contribution to journalArticle

66 Citations (Scopus)

Kinetic and mechanistic studies of carbon-to-metal hydrogen atom transfer involving os-centered radicals: Evidence for tunneling

Lewandowska-Andralojc, A., Grills, D. C., Zhang, J., Bullock, R. M., Miyazawa, A., Kawanishi, Y. & Fujita, E., Mar 5 2014, In : Journal of the American Chemical Society. 136, 9, p. 3572-3578 7 p.

Research output: Contribution to journalArticle

11 Citations (Scopus)

Mechanism of the formation of a Mn-based CO2 reduction catalyst revealed by pulse radiolysis with time-resolved infrared detection

Grills, D. C., Farrington, J. A., Layne, B. H., Lymar, S. V., Mello, B. A., Preses, J. M. & Wishart, J. F., Apr 16 2014, In : Journal of the American Chemical Society. 136, 15, p. 5563-5566 4 p.

Research output: Contribution to journalArticle

65 Citations (Scopus)

Radiation stability of cations in ionic liquids. 5. Task-specific ionic liquids consisting of biocompatible cations and the puzzle of radiation hypersensitivity

Shkrob, I. A., Marin, T. W., Wishart, J. F. & Grills, D. C., Sep 4 2014, In : Journal of Physical Chemistry B. 118, 35, p. 10477-10492 16 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)

Reactivity of a fac-ReCl(α-diimine)(CO)3 complex with an NAD+ model ligand toward CO2 reduction

Matsubara, Y., Hightower, S. E., Chen, J., Grills, D. C., Polyansky, D. E., Muckerman, J. T., Tanaka, K. & Fujita, E., Dec 12 2014, In : Chemical Communications. 50, 6, p. 728-730 3 p.

Research output: Contribution to journalArticle

16 Citations (Scopus)

The reaction of cobaloximes with hydrogen: Products and thermodynamics

Estes, D. P., Grills, D. C. & Norton, J. R., Dec 17 2014, In : Journal of the American Chemical Society. 136, 50, p. 17362-17365 4 p.

Research output: Contribution to journalArticle

65 Citations (Scopus)
2013

Giant infrared absorption bands of electrons and holes in conjugated molecules

Zamadar, M., Asaoka, S., Grills, D. C. & Miller, J. R., Nov 15 2013, In : Nature communications. 4, 2818.

Research output: Contribution to journalArticle

25 Citations (Scopus)

Investigation of monomeric versus dimeric fac-rhenium(I) tricarbonyl systems containing the noninnocent 8-oxyquinolate ligand

Zhao, H. C., Mello, B., Fu, B. L., Chowdhury, H., Szalda, D. J., Tsai, M. K., Grills, D. C. & Rochford, J., Mar 25 2013, In : Organometallics. 32, 6, p. 1832-1841 10 p.

Research output: Contribution to journalArticle

20 Citations (Scopus)

Isolation and X-ray structures of four Rh(PCP) complexes including a Rh(I) dioxygen complex with a short O-O bond

Hayashi, Y., Szalda, D. J., Grills, D. C., Hanson, J. C., Huang, K. W., Muckerman, J. T. & Fujita, E., Jan 1 2013, In : Polyhedron. 58, p. 106-114 9 p.

Research output: Contribution to journalArticle

4 Citations (Scopus)

Kinetics and thermodynamics of small molecule binding to pincer-PCP rhodium(I) complexes

Doherty, M. D., Grills, D. C., Huang, K. W., Muckerman, J. T., Polyansky, D. E., Van Eldik, R. & Fujita, E., Apr 15 2013, In : Inorganic Chemistry. 52, 8, p. 4160-4172 13 p.

Research output: Contribution to journalArticle

11 Citations (Scopus)

Photocatalytic reduction of CO2 under supercritical CO 2 conditions: Effect of pressure, temperature, and solvent on catalytic efficiency

Kawanami, H., Grills, D. C., Ishizaka, T., Chatterjee, M. & Suzuki, A., Oct 28 2013, In : Journal of CO2 Utilization. 3-4, p. 93-97 5 p.

Research output: Contribution to journalArticle

7 Citations (Scopus)
2011

Excited state dependent electron transfer of a rhenium-dipyridophenazine complex intercalated between the base pairs of DNA: A time-resolved UV-visible and IR absorption investigation into the photophysics of fac-[Re(CO) 3(F2dppz)(py)]+ bound to either [poly(dA-dT)]2 or [poly(dG-dC)]2

Cao, Q., Creely, C. M., Davies, E. S., Dyer, J., Easun, T. L., Grills, D. C., McGovern, D. A., McMaster, J., Pitchford, J., Smith, J. A., Sun, X. Z., Kelly, J. M. & George, M. W., Aug 2011, In : Photochemical and Photobiological Sciences. 10, 8, p. 1355-1364 10 p.

Research output: Contribution to journalArticle

25 Citations (Scopus)
2010

Application of external-cavity quantum cascade infrared lasers to nanosecond time-resolved infrared spectroscopy of condensed-phase samples following pulse radiolysis

Grills, D. C., Cook, A. R., Fujita, E., George, M. W., Preses, J. M. & Wishart, J. F., Jun 2010, In : Applied Spectroscopy. 64, 6, p. 563-570 8 p.

Research output: Contribution to journalArticle

23 Citations (Scopus)
80 Citations (Scopus)

Toward more efficient photochemical CO2 reduction: Use of scCO2 or photogenerated hydrides

Doherty, M. D., Grills, D. C., Muckerman, J. T., Polyansky, D. E. & Fujita, E., Nov 1 2010, In : Coordination Chemistry Reviews. 254, 21-22, p. 2472-2482 11 p.

Research output: Contribution to journalReview article

127 Citations (Scopus)
2009
10 Citations (Scopus)
30 Citations (Scopus)
2008

Cell design for picosecond time-resolved infrared spectroscopy in high-pressure liquids and supercritical fluids

Sun, X. Z., Portius, P., Grills, D. C., Cowan, A. J. & George, M. W., Jan 2008, In : Applied Spectroscopy. 62, 1, p. 24-29 6 p.

Research output: Contribution to journalArticle

6 Citations (Scopus)

Photooxidation of guanine by a ruthenium dipyridophenazine complex intercalated in a double-stranded polynucleotide monitored directly by picosecond visible and infrared transient absorption spectroscopy

Elias, B., Creely, C., Doorley, G. W., Feeney, M. M., Moucheron, C., Kirsch-DeMesmaeker, A., Dyer, J., Grills, D. C., George, M. W., Matousek, P., Parker, A. W., Towrie, M. & Kelly, J. M., 2008, In : Chemistry - A European Journal. 14, 1, p. 369-375 7 p.

Research output: Contribution to journalArticle

86 Citations (Scopus)

Selective decarbonylation by a pincer PCP-rhodium(I) complex

Huang, K. W., Grills, D. C., Han, J. H., Szalda, D. J. & Fujita, E., Jul 27 2008, In : Inorganica Chimica Acta. 361, 11, p. 3327-3331 5 p.

Research output: Contribution to journalArticle

21 Citations (Scopus)

Toward photocatalytic CO2 reduction: Synthesis and photophysical characterization of (4,4′-(X) 2-2,2′-bipyridine)ReI(CO)3L complexes

Doherty, M. D., Grills, D. C. & Fujita, E., Dec 1 2008, American Chemical Society - 236th National Meeting and Exposition, Abstracts of Scientific Papers. (ACS National Meeting Book of Abstracts).

Research output: Chapter in Book/Report/Conference proceedingConference contribution

2007

Metal-dependent reactivity differences for transients formed by flash photolysis of (PNP)M(CO), M = Co and Rh

Rimmer, R. D., Grills, D. C., Fan, H., Ford, P. C. & Caulton, K. G., Dec 19 2007, In : Journal of the American Chemical Society. 129, 50, p. 15430-15431 2 p.

Research output: Contribution to journalArticle

9 Citations (Scopus)
25 Citations (Scopus)

Solvent dependent photophysics of fac-[Re(CO)3(11,12-X 2dppz)(py)]+ (X = H, F or Me)

Dyer, J., Creely, C. M., Penedo, J. C., Grills, D. C., Hudson, S., Matousek, P., Parker, A. W., Towrie, M., Kelly, J. M. & George, M. W., 2007, In : Photochemical and Photobiological Sciences. 6, 7, p. 741-748 8 p.

Research output: Contribution to journalArticle

29 Citations (Scopus)
26 Citations (Scopus)

Time-resolved infrared (TRIR) study on the formation and reactivity of organometallic methane and ethane complexes in room temperature solution

Cowan, A. J., Portius, P., Kawanami, H. K., Jina, O. S., Grills, D. C., Sun, X. Z., McMaster, J. & George, M. W., Apr 24 2007, In : Proceedings of the National Academy of Sciences of the United States of America. 104, 17, p. 6933-6938 6 p.

Research output: Contribution to journalArticle

39 Citations (Scopus)
2006

Development of a broadband picosecond infrared spectrometer and its incorporation into an existing ultrafast time-resolved resonance raman, UV/visible, and fluorescence spectroscopic apparatus

Towrie, M., Grills, D. C., Dyer, J., Weinstein, J. A., Matousek, P., Barton, R., Bailey, P. D., Subramaniam, N., Kwok, W. M., Ma, C., Phillips, D., Parker, A. W. & George, M. W., Jan 1 2006, The Life and Scientific Legacy of George Porter. Imperial College Press, p. 454-467 14 p.

Research output: Chapter in Book/Report/Conference proceedingChapter

10 Citations (Scopus)
10 Citations (Scopus)