α-RuCl3

a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites

L. Wang, P. Brazis, M. Rocci, C. R. Kannewurf, Mercouri G Kanatzidis

Research output: Chapter in Book/Report/Conference proceedingConference contribution

7 Citations (Scopus)

Abstract

α-RuCl3 was identified as a new host for polymer intercalation using different intercalative methods. It is found that Li0.2RuCl3 exfoliates in water into single [RuCl3]x- layers which can be used to encapsulate macromolecules. RuCl3/polymer nanocomposites such as Li0.2(PEO)xRuCl3 (PEO=poly[ethylene oxide]), Li0.2(PVP)xRuCl3 (PVP=polyvinylpyrrolidone) and (PPY)xRuCl3 (PPY=polypyrrole) were successfully prepared. (PANI)xRuCl3 (PANI=polyaniline) was prepared by in situ intercalative polymerization directly from α-RuCl3. These nanocomposites were characterized with Thermogravimetric Analysis (TGA), Infrared spectroscopy (IR), Powder X-ray Diffraction (XRD), magnetic measurements, conductivity measurements and thermopower measurements.

Original languageEnglish
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsR.M. Laine, C. Sanchez, C.J. Brinker, E. Ciannelis
PublisherMRS
Pages257-264
Number of pages8
Volume519
Publication statusPublished - 1998
EventProceedings of the 1998 MRS Spring Symposium - San Francisco, CA, USA
Duration: Apr 13 1998Apr 17 1998

Other

OtherProceedings of the 1998 MRS Spring Symposium
CitySan Francisco, CA, USA
Period4/13/984/17/98

Fingerprint

Intercalation
Polyethylene oxides
Povidone
Nanocomposites
Polymers
Thermoelectric power
Magnetic variables measurement
Polypyrroles
Polyaniline
Macromolecules
X ray powder diffraction
Thermogravimetric analysis
Infrared spectroscopy
Polymerization
Water

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Wang, L., Brazis, P., Rocci, M., Kannewurf, C. R., & Kanatzidis, M. G. (1998). α-RuCl3: a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites. In R. M. Laine, C. Sanchez, C. J. Brinker, & E. Ciannelis (Eds.), Materials Research Society Symposium - Proceedings (Vol. 519, pp. 257-264). MRS.

α-RuCl3 : a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites. / Wang, L.; Brazis, P.; Rocci, M.; Kannewurf, C. R.; Kanatzidis, Mercouri G.

Materials Research Society Symposium - Proceedings. ed. / R.M. Laine; C. Sanchez; C.J. Brinker; E. Ciannelis. Vol. 519 MRS, 1998. p. 257-264.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Wang, L, Brazis, P, Rocci, M, Kannewurf, CR & Kanatzidis, MG 1998, α-RuCl3: a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites. in RM Laine, C Sanchez, CJ Brinker & E Ciannelis (eds), Materials Research Society Symposium - Proceedings. vol. 519, MRS, pp. 257-264, Proceedings of the 1998 MRS Spring Symposium, San Francisco, CA, USA, 4/13/98.
Wang L, Brazis P, Rocci M, Kannewurf CR, Kanatzidis MG. α-RuCl3: a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites. In Laine RM, Sanchez C, Brinker CJ, Ciannelis E, editors, Materials Research Society Symposium - Proceedings. Vol. 519. MRS. 1998. p. 257-264
Wang, L. ; Brazis, P. ; Rocci, M. ; Kannewurf, C. R. ; Kanatzidis, Mercouri G. / α-RuCl3 : a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites. Materials Research Society Symposium - Proceedings. editor / R.M. Laine ; C. Sanchez ; C.J. Brinker ; E. Ciannelis. Vol. 519 MRS, 1998. pp. 257-264
@inproceedings{b33c18519c01486d9c43dbed8b87a00a,
title = "α-RuCl3: a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites",
abstract = "α-RuCl3 was identified as a new host for polymer intercalation using different intercalative methods. It is found that Li0.2RuCl3 exfoliates in water into single [RuCl3]x- layers which can be used to encapsulate macromolecules. RuCl3/polymer nanocomposites such as Li0.2(PEO)xRuCl3 (PEO=poly[ethylene oxide]), Li0.2(PVP)xRuCl3 (PVP=polyvinylpyrrolidone) and (PPY)xRuCl3 (PPY=polypyrrole) were successfully prepared. (PANI)xRuCl3 (PANI=polyaniline) was prepared by in situ intercalative polymerization directly from α-RuCl3. These nanocomposites were characterized with Thermogravimetric Analysis (TGA), Infrared spectroscopy (IR), Powder X-ray Diffraction (XRD), magnetic measurements, conductivity measurements and thermopower measurements.",
author = "L. Wang and P. Brazis and M. Rocci and Kannewurf, {C. R.} and Kanatzidis, {Mercouri G}",
year = "1998",
language = "English",
volume = "519",
pages = "257--264",
editor = "R.M. Laine and C. Sanchez and C.J. Brinker and E. Ciannelis",
booktitle = "Materials Research Society Symposium - Proceedings",
publisher = "MRS",

}

TY - GEN

T1 - α-RuCl3

T2 - a new host for polymer intercalation. Lamellar polymer/α-RuCl3 nanocomposites

AU - Wang, L.

AU - Brazis, P.

AU - Rocci, M.

AU - Kannewurf, C. R.

AU - Kanatzidis, Mercouri G

PY - 1998

Y1 - 1998

N2 - α-RuCl3 was identified as a new host for polymer intercalation using different intercalative methods. It is found that Li0.2RuCl3 exfoliates in water into single [RuCl3]x- layers which can be used to encapsulate macromolecules. RuCl3/polymer nanocomposites such as Li0.2(PEO)xRuCl3 (PEO=poly[ethylene oxide]), Li0.2(PVP)xRuCl3 (PVP=polyvinylpyrrolidone) and (PPY)xRuCl3 (PPY=polypyrrole) were successfully prepared. (PANI)xRuCl3 (PANI=polyaniline) was prepared by in situ intercalative polymerization directly from α-RuCl3. These nanocomposites were characterized with Thermogravimetric Analysis (TGA), Infrared spectroscopy (IR), Powder X-ray Diffraction (XRD), magnetic measurements, conductivity measurements and thermopower measurements.

AB - α-RuCl3 was identified as a new host for polymer intercalation using different intercalative methods. It is found that Li0.2RuCl3 exfoliates in water into single [RuCl3]x- layers which can be used to encapsulate macromolecules. RuCl3/polymer nanocomposites such as Li0.2(PEO)xRuCl3 (PEO=poly[ethylene oxide]), Li0.2(PVP)xRuCl3 (PVP=polyvinylpyrrolidone) and (PPY)xRuCl3 (PPY=polypyrrole) were successfully prepared. (PANI)xRuCl3 (PANI=polyaniline) was prepared by in situ intercalative polymerization directly from α-RuCl3. These nanocomposites were characterized with Thermogravimetric Analysis (TGA), Infrared spectroscopy (IR), Powder X-ray Diffraction (XRD), magnetic measurements, conductivity measurements and thermopower measurements.

UR - http://www.scopus.com/inward/record.url?scp=0032289577&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0032289577&partnerID=8YFLogxK

M3 - Conference contribution

VL - 519

SP - 257

EP - 264

BT - Materials Research Society Symposium - Proceedings

A2 - Laine, R.M.

A2 - Sanchez, C.

A2 - Brinker, C.J.

A2 - Ciannelis, E.

PB - MRS

ER -