β-Bi4(P2Se6)3: A new ternary selenophosphate obtained in a P2Se5 flux

Jennifer A. Aitken; Shannon Brown; Konstantinos Chondroudis; Stéphane Jobic; Raymond Brec; Mercouri G. Kanatzidis

β-Bi₄(P₂Se₆)₃: A new ternary selenophosphate obtained in a P₂Se₅ flux

Jennifer A. Aitken, Shannon Brown, Konstantinos Chondroudis, Stéphane Jobic, Raymond Brec, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Bi metal dissolves in excess molten phosphorus selenide at 500 °C to yield black, rodlike, air- and water-stable β-Bi₄(P₂Se₆)₃ crystals. The phase crystallizes in the triclinic space group P1̄ (No. 2) with the room-temperature cell parameters a = 12.2303(8) Å, b = 6.7640(4) Å, c = 17.866 Å, α = 90.493(6)°, β = 94.133(6)°, and γ = 91.163(6)°. The new structure is a complicated, three-dimensional framework built from [Bi₄Se₂₂] ribbons connected to each other by sharing selenium atoms. The [P₂Se₆]^4- ethane-like units are found inside and between the [Bi₄Se₂₂] ribbons. The compound is a semiconductor with a band gap of 1.32 eV. It melts with decomposition at 512 °C, converting partially to Bi₂Se₃ and a P_xSe_y glassy material. Far-IR and Raman spectra show characteristic stretches for the [P₂Se₆]^4- ligand and Bi-Se vibrations. The structural and chemical relationships of this compound with the α-form are discussed.

Original language	English
Pages (from-to)	4795-4800
Number of pages	6
Journal	Inorganic Chemistry
Volume	38
Issue number	21
Publication status	Published - Dec 1 1999

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "β-Bi4(P2Se6)3: A new ternary selenophosphate obtained in a P2Se5 flux",

abstract = "Bi metal dissolves in excess molten phosphorus selenide at 500 °C to yield black, rodlike, air- and water-stable β-Bi4(P2Se6)3 crystals. The phase crystallizes in the triclinic space group P{\=1} (No. 2) with the room-temperature cell parameters a = 12.2303(8) {\AA}, b = 6.7640(4) {\AA}, c = 17.866 {\AA}, α = 90.493(6)°, β = 94.133(6)°, and γ = 91.163(6)°. The new structure is a complicated, three-dimensional framework built from [Bi4Se22] ribbons connected to each other by sharing selenium atoms. The [P2Se6]4- ethane-like units are found inside and between the [Bi4Se22] ribbons. The compound is a semiconductor with a band gap of 1.32 eV. It melts with decomposition at 512 °C, converting partially to Bi2Se3 and a PxSey glassy material. Far-IR and Raman spectra show characteristic stretches for the [P2Se6]4- ligand and Bi-Se vibrations. The structural and chemical relationships of this compound with the α-form are discussed.",

author = "Aitken, {Jennifer A.} and Shannon Brown and Konstantinos Chondroudis and St{\'e}phane Jobic and Raymond Brec and Kanatzidis, {Mercouri G.}",

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T2 - A new ternary selenophosphate obtained in a P2Se5 flux

AU - Aitken, Jennifer A.

AU - Brown, Shannon

AU - Chondroudis, Konstantinos

AU - Jobic, Stéphane

AU - Brec, Raymond

AU - Kanatzidis, Mercouri G.

PY - 1999/12/1

Y1 - 1999/12/1

N2 - Bi metal dissolves in excess molten phosphorus selenide at 500 °C to yield black, rodlike, air- and water-stable β-Bi4(P2Se6)3 crystals. The phase crystallizes in the triclinic space group P1̄ (No. 2) with the room-temperature cell parameters a = 12.2303(8) Å, b = 6.7640(4) Å, c = 17.866 Å, α = 90.493(6)°, β = 94.133(6)°, and γ = 91.163(6)°. The new structure is a complicated, three-dimensional framework built from [Bi4Se22] ribbons connected to each other by sharing selenium atoms. The [P2Se6]4- ethane-like units are found inside and between the [Bi4Se22] ribbons. The compound is a semiconductor with a band gap of 1.32 eV. It melts with decomposition at 512 °C, converting partially to Bi2Se3 and a PxSey glassy material. Far-IR and Raman spectra show characteristic stretches for the [P2Se6]4- ligand and Bi-Se vibrations. The structural and chemical relationships of this compound with the α-form are discussed.

AB - Bi metal dissolves in excess molten phosphorus selenide at 500 °C to yield black, rodlike, air- and water-stable β-Bi4(P2Se6)3 crystals. The phase crystallizes in the triclinic space group P1̄ (No. 2) with the room-temperature cell parameters a = 12.2303(8) Å, b = 6.7640(4) Å, c = 17.866 Å, α = 90.493(6)°, β = 94.133(6)°, and γ = 91.163(6)°. The new structure is a complicated, three-dimensional framework built from [Bi4Se22] ribbons connected to each other by sharing selenium atoms. The [P2Se6]4- ethane-like units are found inside and between the [Bi4Se22] ribbons. The compound is a semiconductor with a band gap of 1.32 eV. It melts with decomposition at 512 °C, converting partially to Bi2Se3 and a PxSey glassy material. Far-IR and Raman spectra show characteristic stretches for the [P2Se6]4- ligand and Bi-Se vibrations. The structural and chemical relationships of this compound with the α-form are discussed.

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β-Bi₄(P₂Se₆)₃: A new ternary selenophosphate obtained in a P₂Se₅ flux

Abstract

ASJC Scopus subject areas

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