1-D infinite array of metalloporphyrin cages

Long Pan, Xiaoying Huang, Hoa Loan N Phan, T. J. Emge, Jing Li, Xiaotai Wang

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H 2DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co3(DPyP)3]·4HDMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co3(DPyP)3]·4DMF at 130 °C generates [Co3(DPyP)3] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co3(DPyP)3·4HDMF.

Original languageEnglish
Pages (from-to)6878-6880
Number of pages3
JournalInorganic Chemistry
Volume43
Issue number22
DOIs
Publication statusPublished - Nov 1 2004

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Metalloporphyrins
Porphyrins
Diffraction patterns
ribbons
Polymers
Metals
Ligands
Molecules
coordination polymers
porphyrins
crystallinity
diffraction patterns
ligands
metals
molecules
x rays

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Pan, L., Huang, X., Phan, H. L. N., Emge, T. J., Li, J., & Wang, X. (2004). 1-D infinite array of metalloporphyrin cages. Inorganic Chemistry, 43(22), 6878-6880. https://doi.org/10.1021/ic049141i

1-D infinite array of metalloporphyrin cages. / Pan, Long; Huang, Xiaoying; Phan, Hoa Loan N; Emge, T. J.; Li, Jing; Wang, Xiaotai.

In: Inorganic Chemistry, Vol. 43, No. 22, 01.11.2004, p. 6878-6880.

Research output: Contribution to journalArticle

Pan, L, Huang, X, Phan, HLN, Emge, TJ, Li, J & Wang, X 2004, '1-D infinite array of metalloporphyrin cages', Inorganic Chemistry, vol. 43, no. 22, pp. 6878-6880. https://doi.org/10.1021/ic049141i
Pan L, Huang X, Phan HLN, Emge TJ, Li J, Wang X. 1-D infinite array of metalloporphyrin cages. Inorganic Chemistry. 2004 Nov 1;43(22):6878-6880. https://doi.org/10.1021/ic049141i
Pan, Long ; Huang, Xiaoying ; Phan, Hoa Loan N ; Emge, T. J. ; Li, Jing ; Wang, Xiaotai. / 1-D infinite array of metalloporphyrin cages. In: Inorganic Chemistry. 2004 ; Vol. 43, No. 22. pp. 6878-6880.
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