(4NPEA) 2 PbI 4 (4NPEA = 4-Nitrophenylethylammonium): Structural, NMR, and Optical Properties of a 3 × 3 Corrugated 2D Hybrid Perovskite

Marie Hélène Tremblay, Félix Thouin, Johannes Leisen, John Bacsa, Ajay Ram Srimath Kandada, Justin M. Hoffman, Mercouri G Kanatzidis, Aditya D. Mohite, Carlos Silva, Stephen Barlow, Seth R. Marder

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

(4NPEA) 2 PbI 4 (4NPEA = 4-nitrophenylethylammonium) is the first 3 × 3 corrugated 2D organic-Pb/I perovskite. The nitro groups are involved in cation-cation and cation-iodide interactions. The structure contains both highly distorted and near-ideal PbI 6 octahedra, consistent with the observation of two 207 Pb NMR resonances, while the optical properties resemble those of other 2D perovskites with distorted PbI 6 octahedra.

Original languageEnglish
Pages (from-to)4521-4525
Number of pages5
JournalJournal of the American Chemical Society
Volume141
Issue number11
DOIs
Publication statusPublished - Mar 20 2019

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Perovskite
Cations
Optical properties
Positive ions
Nuclear magnetic resonance
Iodides
Observation
perovskite

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Tremblay, M. H., Thouin, F., Leisen, J., Bacsa, J., Srimath Kandada, A. R., Hoffman, J. M., ... Marder, S. R. (2019). (4NPEA) 2 PbI 4 (4NPEA = 4-Nitrophenylethylammonium): Structural, NMR, and Optical Properties of a 3 × 3 Corrugated 2D Hybrid Perovskite. Journal of the American Chemical Society, 141(11), 4521-4525. https://doi.org/10.1021/jacs.8b13207

(4NPEA) 2 PbI 4 (4NPEA = 4-Nitrophenylethylammonium) : Structural, NMR, and Optical Properties of a 3 × 3 Corrugated 2D Hybrid Perovskite. / Tremblay, Marie Hélène; Thouin, Félix; Leisen, Johannes; Bacsa, John; Srimath Kandada, Ajay Ram; Hoffman, Justin M.; Kanatzidis, Mercouri G; Mohite, Aditya D.; Silva, Carlos; Barlow, Stephen; Marder, Seth R.

In: Journal of the American Chemical Society, Vol. 141, No. 11, 20.03.2019, p. 4521-4525.

Research output: Contribution to journalArticle

Tremblay, MH, Thouin, F, Leisen, J, Bacsa, J, Srimath Kandada, AR, Hoffman, JM, Kanatzidis, MG, Mohite, AD, Silva, C, Barlow, S & Marder, SR 2019, '(4NPEA) 2 PbI 4 (4NPEA = 4-Nitrophenylethylammonium): Structural, NMR, and Optical Properties of a 3 × 3 Corrugated 2D Hybrid Perovskite', Journal of the American Chemical Society, vol. 141, no. 11, pp. 4521-4525. https://doi.org/10.1021/jacs.8b13207
Tremblay, Marie Hélène ; Thouin, Félix ; Leisen, Johannes ; Bacsa, John ; Srimath Kandada, Ajay Ram ; Hoffman, Justin M. ; Kanatzidis, Mercouri G ; Mohite, Aditya D. ; Silva, Carlos ; Barlow, Stephen ; Marder, Seth R. / (4NPEA) 2 PbI 4 (4NPEA = 4-Nitrophenylethylammonium) : Structural, NMR, and Optical Properties of a 3 × 3 Corrugated 2D Hybrid Perovskite. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 11. pp. 4521-4525.
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