A catalytically active, permanently microporous MOF with metalloporphyrin struts

Abraham M. Shultz; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/ja900203f

A catalytically active, permanently microporous MOF with metalloporphyrin struts

Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, Sonbinh T. Nguyen

Northwestern University

Research output: Contribution to journal › Article

446 Citations (Scopus)

Abstract

Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

Original language	English
Pages (from-to)	4204-4205
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	12
DOIs	https://doi.org/10.1021/ja900203f
Publication status	Published - Apr 1 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja900203f

Fingerprint Dive into the research topics of 'A catalytically active, permanently microporous MOF with metalloporphyrin struts'. Together they form a unique fingerprint.

Cite this

Shultz, A. M., Farha, O. K., Hupp, J. T., & Nguyen, S. T. (2009). A catalytically active, permanently microporous MOF with metalloporphyrin struts. Journal of the American Chemical Society, 131(12), 4204-4205. https://doi.org/10.1021/ja900203f

@article{c096d4b4480a441a976b001f474c4866,

title = "A catalytically active, permanently microporous MOF with metalloporphyrin struts",

abstract = "Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.",

author = "Shultz, {Abraham M.} and Farha, {Omar K.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

year = "2009",

month = apr,

day = "1",

doi = "10.1021/ja900203f",

language = "English",

volume = "131",

pages = "4204--4205",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "12",

}

TY - JOUR

T1 - A catalytically active, permanently microporous MOF with metalloporphyrin struts

AU - Shultz, Abraham M.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2009/4/1

Y1 - 2009/4/1

N2 - Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

AB - Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

UR - http://www.scopus.com/inward/record.url?scp=67749145470&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=67749145470&partnerID=8YFLogxK

U2 - 10.1021/ja900203f

DO - 10.1021/ja900203f

M3 - Article

C2 - 19271705

AN - SCOPUS:67749145470

VL - 131

SP - 4204

EP - 4205

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

SN - 0002-7863

IS - 12

ER -