Abstract
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
Original language | English |
---|---|
Pages (from-to) | 4204-4205 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 131 |
Issue number | 12 |
DOIs | |
Publication status | Published - Apr 1 2009 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry