Abstract
Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
| Original language | English |
|---|---|
| Pages (from-to) | 4204-4205 |
| Number of pages | 2 |
| Journal | Journal of the American Chemical Society |
| Volume | 131 |
| Issue number | 12 |
| DOIs | |
| Publication status | Published - Apr 1 2009 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Biochemistry
- Colloid and Surface Chemistry
Cite this
A catalytically active, permanently microporous MOF with metalloporphyrin struts. / Shultz, Abraham M.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.
In: Journal of the American Chemical Society, Vol. 131, No. 12, 01.04.2009, p. 4204-4205.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A catalytically active, permanently microporous MOF with metalloporphyrin struts
AU - Shultz, Abraham M.
AU - Farha, Omar K.
AU - Hupp, Joseph T
AU - Nguyen, Sonbinh T.
PY - 2009/4/1
Y1 - 2009/4/1
N2 - Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
AB - Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.
UR - http://www.scopus.com/inward/record.url?scp=67749145470&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=67749145470&partnerID=8YFLogxK
U2 - 10.1021/ja900203f
DO - 10.1021/ja900203f
M3 - Article
VL - 131
SP - 4204
EP - 4205
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 12
ER -