A catalytically active, permanently microporous MOF with metalloporphyrin struts

Abraham M. Shultz; Omar K. Farha; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/ja900203f

A catalytically active, permanently microporous MOF with metalloporphyrin struts

Abraham M. Shultz, Omar K. Farha, Joseph T. Hupp, Sonbinh T. Nguyen

Northwestern University

Research output: Contribution to journal › Article › peer-review

457 Citations (Scopus)

Abstract

Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

Original language	English
Pages (from-to)	4204-4205
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	131
Issue number	12
DOIs	https://doi.org/10.1021/ja900203f
Publication status	Published - Apr 1 2009

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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AB - Through the use of the tetratopic ligand 1,2,4,5-tetrakis(4-carboxyphenyl) benzene as a key building block, a permanently microporous metal-organic framework with Lewis acidic (porphyrin)Zn struts, ZnPO-MOF, can be made in high yields. ZnPO-MOF can efficiently catalyze acyl-transfer reactions primarily by preconcentrating the substrates within its pores, in stark contrast to analogous supramolecular systems.

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A catalytically active, permanently microporous MOF with metalloporphyrin struts

Abstract

ASJC Scopus subject areas

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