A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

Huong Giang T Nguyen, Mitchell H. Weston, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

37 Citations (Scopus)

Abstract

A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

Original languageEnglish
Pages (from-to)4115-4118
Number of pages4
JournalCrystEngComm
Volume14
Issue number12
DOIs
Publication statusPublished - Jun 21 2012

Fingerprint

sulfoxide
tert-Butylhydroperoxide
Vanadates
Sulfides
Oxidants
sulfides
Metals
catalysts
Oxidation
oxidation
Catalysts
synthesis
products
metals

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications. / Nguyen, Huong Giang T; Weston, Mitchell H.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: CrystEngComm, Vol. 14, No. 12, 21.06.2012, p. 4115-4118.

Research output: Contribution to journalArticle

Nguyen, Huong Giang T ; Weston, Mitchell H. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications. In: CrystEngComm. 2012 ; Vol. 14, No. 12. pp. 4115-4118.
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