A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

Huong Giang T. Nguyen, Mitchell H. Weston, Omar K. Farha, Joseph T. Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

39 Citations (Scopus)

Abstract

A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

Original languageEnglish
Pages (from-to)4115-4118
Number of pages4
JournalCrystEngComm
Volume14
Issue number12
DOIs
Publication statusPublished - Jun 21 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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