A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion

Christopher J. Wood, Gareth H. Summers, Charlotte A. Clark, Nicolas Kaeffer, Maximilian Braeutigam, Lea Roberta Carbone, Luca D'Amario, Ke Fan, Yoann Farré, Stéphanie Narbey, Frédéric Oswald, Lee A. Stevens, Christopher D J Parmenter, Michael W. Fay, Alessandro La Torre, Colin E. Snape, Benjamin Dietzek, Danilo Dini, Leif Hammarström, Yann PellegrinFabrice Odobel, Licheng Sun, Vincent Artero, Elizabeth A. Gibson

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

We investigated a range of different mesoporous NiO electrodes prepared by different research groups and private firms in Europe to determine the parameters which influence good quality photoelectrochemical devices. This benchmarking study aims to solve some of the discrepancies in the literature regarding the performance of p-DSCs due to differences in the quality of the device fabrication. The information obtained will lay the foundation for future photocatalytic systems based on sensitized NiO so that new dyes and catalysts can be tested with a standardized material. The textural and electrochemical properties of the semiconducting material are key to the performance of photocathodes. We found that both commercial and non-commercial NiO gave promising solar cell and water-splitting devices. The NiO samples which had the two highest solar cell efficiency (0.145% and 0.089%) also gave the best overall theoretical H2 conversion.

Original languageEnglish
Pages (from-to)10727-10738
Number of pages12
JournalPhysical Chemistry Chemical Physics
Volume18
Issue number16
DOIs
Publication statusPublished - Apr 28 2016

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solar energy conversion
Photocathodes
photocathodes
Energy conversion
Solar energy
Solar cells
photoelectrochemical devices
Coloring Agents
solar cells
dyes
water splitting
Benchmarking
Electrochemical properties
catalysts
Fabrication
Electrodes
Catalysts
fabrication
electrodes
Water

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Physics and Astronomy(all)

Cite this

Wood, C. J., Summers, G. H., Clark, C. A., Kaeffer, N., Braeutigam, M., Carbone, L. R., ... Gibson, E. A. (2016). A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion. Physical Chemistry Chemical Physics, 18(16), 10727-10738. https://doi.org/10.1039/c5cp05326a

A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion. / Wood, Christopher J.; Summers, Gareth H.; Clark, Charlotte A.; Kaeffer, Nicolas; Braeutigam, Maximilian; Carbone, Lea Roberta; D'Amario, Luca; Fan, Ke; Farré, Yoann; Narbey, Stéphanie; Oswald, Frédéric; Stevens, Lee A.; Parmenter, Christopher D J; Fay, Michael W.; La Torre, Alessandro; Snape, Colin E.; Dietzek, Benjamin; Dini, Danilo; Hammarström, Leif; Pellegrin, Yann; Odobel, Fabrice; Sun, Licheng; Artero, Vincent; Gibson, Elizabeth A.

In: Physical Chemistry Chemical Physics, Vol. 18, No. 16, 28.04.2016, p. 10727-10738.

Research output: Contribution to journalArticle

Wood, CJ, Summers, GH, Clark, CA, Kaeffer, N, Braeutigam, M, Carbone, LR, D'Amario, L, Fan, K, Farré, Y, Narbey, S, Oswald, F, Stevens, LA, Parmenter, CDJ, Fay, MW, La Torre, A, Snape, CE, Dietzek, B, Dini, D, Hammarström, L, Pellegrin, Y, Odobel, F, Sun, L, Artero, V & Gibson, EA 2016, 'A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion', Physical Chemistry Chemical Physics, vol. 18, no. 16, pp. 10727-10738. https://doi.org/10.1039/c5cp05326a
Wood CJ, Summers GH, Clark CA, Kaeffer N, Braeutigam M, Carbone LR et al. A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion. Physical Chemistry Chemical Physics. 2016 Apr 28;18(16):10727-10738. https://doi.org/10.1039/c5cp05326a
Wood, Christopher J. ; Summers, Gareth H. ; Clark, Charlotte A. ; Kaeffer, Nicolas ; Braeutigam, Maximilian ; Carbone, Lea Roberta ; D'Amario, Luca ; Fan, Ke ; Farré, Yoann ; Narbey, Stéphanie ; Oswald, Frédéric ; Stevens, Lee A. ; Parmenter, Christopher D J ; Fay, Michael W. ; La Torre, Alessandro ; Snape, Colin E. ; Dietzek, Benjamin ; Dini, Danilo ; Hammarström, Leif ; Pellegrin, Yann ; Odobel, Fabrice ; Sun, Licheng ; Artero, Vincent ; Gibson, Elizabeth A. / A comprehensive comparison of dye-sensitized NiO photocathodes for solar energy conversion. In: Physical Chemistry Chemical Physics. 2016 ; Vol. 18, No. 16. pp. 10727-10738.
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