Abstract
Ethanol-soluble amphiphilic TiO2 nanoparticles (NPs) of average diameter ∼9 nm were synthesized, and an α-terpineol-based TiO 2 paste was readily prepared from them in comparatively few steps. When used for fabrication of photoelectrodes for dye-sensitized solar cells (DSSCs), the paste yielded highly transparent films and possessing greater-than-typical, thickness-normalized surface areas. These film properties enabled the corresponding DSSCs to produce high photocurrent densities (17.7 mA cm-2) and a comparatively high overall light-to-electrical energy conversion efficiency (9.6%) when deployed with the well-known ruthenium-based molecular dye, N719. These efficiencies are about ∼1.4 times greater than those obtained from DSSCs containing photoelectrodes derived from a standard commercial source of TiO2 paste.
| Original language | English |
|---|---|
| Pages (from-to) | 1996-1999 |
| Number of pages | 4 |
| Journal | Langmuir |
| Volume | 27 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Mar 1 2011 |
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ASJC Scopus subject areas
- Electrochemistry
- Condensed Matter Physics
- Surfaces and Interfaces
- Materials Science(all)
- Spectroscopy
Cite this
A convenient route to high area, nanoparticulate TiO2 photoelectrodes suitable for high-efficiency energy conversion in dye-sensitized solar cells. / Jeong, Nak Cheon; Farha, Omar K.; Hupp, Joseph T.
In: Langmuir, Vol. 27, No. 5, 01.03.2011, p. 1996-1999.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A convenient route to high area, nanoparticulate TiO2 photoelectrodes suitable for high-efficiency energy conversion in dye-sensitized solar cells
AU - Jeong, Nak Cheon
AU - Farha, Omar K.
AU - Hupp, Joseph T
PY - 2011/3/1
Y1 - 2011/3/1
N2 - Ethanol-soluble amphiphilic TiO2 nanoparticles (NPs) of average diameter ∼9 nm were synthesized, and an α-terpineol-based TiO 2 paste was readily prepared from them in comparatively few steps. When used for fabrication of photoelectrodes for dye-sensitized solar cells (DSSCs), the paste yielded highly transparent films and possessing greater-than-typical, thickness-normalized surface areas. These film properties enabled the corresponding DSSCs to produce high photocurrent densities (17.7 mA cm-2) and a comparatively high overall light-to-electrical energy conversion efficiency (9.6%) when deployed with the well-known ruthenium-based molecular dye, N719. These efficiencies are about ∼1.4 times greater than those obtained from DSSCs containing photoelectrodes derived from a standard commercial source of TiO2 paste.
AB - Ethanol-soluble amphiphilic TiO2 nanoparticles (NPs) of average diameter ∼9 nm were synthesized, and an α-terpineol-based TiO 2 paste was readily prepared from them in comparatively few steps. When used for fabrication of photoelectrodes for dye-sensitized solar cells (DSSCs), the paste yielded highly transparent films and possessing greater-than-typical, thickness-normalized surface areas. These film properties enabled the corresponding DSSCs to produce high photocurrent densities (17.7 mA cm-2) and a comparatively high overall light-to-electrical energy conversion efficiency (9.6%) when deployed with the well-known ruthenium-based molecular dye, N719. These efficiencies are about ∼1.4 times greater than those obtained from DSSCs containing photoelectrodes derived from a standard commercial source of TiO2 paste.
UR - http://www.scopus.com/inward/record.url?scp=79951882868&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79951882868&partnerID=8YFLogxK
U2 - 10.1021/la104297s
DO - 10.1021/la104297s
M3 - Article
C2 - 21250741
AN - SCOPUS:79951882868
VL - 27
SP - 1996
EP - 1999
JO - Langmuir
JF - Langmuir
SN - 0743-7463
IS - 5
ER -