A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components

Michelle Absi, Charlotte L. Stern, Dong I. Yoon, Joseph T Hupp

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The structure of the title assembly, tricarbonylchloro-[16-nitro-3,6,9,12,20,23,26,29-octaoxa-34,37-diazatetra- cyclo[34.3.1.114,18.1 31,35]dotetraconta-1(39),14,16,18(41),-31, 33, 35(42), 36(40), 37-nonaene-2, 13, 19, 30-tetrone]-rhenium(I), [ReCl(C32H33N3O14)(CO)3], has been determined via a single-crystal diffraction study. The rhenium ion is octahedrally coordinated. The bidentate bipyridine/crown ether/nitrobenzene assembly is folded such that the pyridyl rings and nitrobenzene moiety are almost coplanar.

Original languageEnglish
Pages (from-to)1054-1055
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume53
Issue number8
Publication statusPublished - Aug 15 1997

Fingerprint

Rhenium
nitrobenzenes
rhenium
Crowns
assembly
Crown Ethers
ethers
Diffraction
Single crystals
Ions
rings
single crystals
diffraction
ions
nitrobenzene

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

A crown-linked donor-acceptor assembly containing ReI(diimine)(CO)3Cl and nitrobenzene components. / Absi, Michelle; Stern, Charlotte L.; Yoon, Dong I.; Hupp, Joseph T.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 53, No. 8, 15.08.1997, p. 1054-1055.

Research output: Contribution to journalArticle

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