A dual approach to tuning the porosity of porous organic polymers

Controlling the porogen size and supercritical CO2 processing

Ryan K. Totten, Laura L. Olenick, Ye Seong Kim, Sanjiban Chakraborty, Mitchell H. Weston, Omar K. Farha, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of SnIV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO2 processing resulted in excellent enhancements of the total pore volumes.

Original languageEnglish
Pages (from-to)782-787
Number of pages6
JournalChemical Science
Volume5
Issue number2
DOIs
Publication statusPublished - Feb 2014

Fingerprint

Organic polymers
Tuning
Porosity
Ligands
Porphyrins
Processing

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Totten, R. K., Olenick, L. L., Kim, Y. S., Chakraborty, S., Weston, M. H., Farha, O. K., ... Nguyen, S. T. (2014). A dual approach to tuning the porosity of porous organic polymers: Controlling the porogen size and supercritical CO2 processing. Chemical Science, 5(2), 782-787. https://doi.org/10.1039/c3sc52010b

A dual approach to tuning the porosity of porous organic polymers : Controlling the porogen size and supercritical CO2 processing. / Totten, Ryan K.; Olenick, Laura L.; Kim, Ye Seong; Chakraborty, Sanjiban; Weston, Mitchell H.; Farha, Omar K.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Chemical Science, Vol. 5, No. 2, 02.2014, p. 782-787.

Research output: Contribution to journalArticle

Totten, Ryan K. ; Olenick, Laura L. ; Kim, Ye Seong ; Chakraborty, Sanjiban ; Weston, Mitchell H. ; Farha, Omar K. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / A dual approach to tuning the porosity of porous organic polymers : Controlling the porogen size and supercritical CO2 processing. In: Chemical Science. 2014 ; Vol. 5, No. 2. pp. 782-787.
@article{1005af5ab893457eaaac66707d4bd5ef,
title = "A dual approach to tuning the porosity of porous organic polymers: Controlling the porogen size and supercritical CO2 processing",
abstract = "Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of SnIV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO2 processing resulted in excellent enhancements of the total pore volumes.",
author = "Totten, {Ryan K.} and Olenick, {Laura L.} and Kim, {Ye Seong} and Sanjiban Chakraborty and Weston, {Mitchell H.} and Farha, {Omar K.} and Hupp, {Joseph T} and Nguyen, {Sonbinh T.}",
year = "2014",
month = "2",
doi = "10.1039/c3sc52010b",
language = "English",
volume = "5",
pages = "782--787",
journal = "Chemical Science",
issn = "2041-6520",
publisher = "Royal Society of Chemistry",
number = "2",

}

TY - JOUR

T1 - A dual approach to tuning the porosity of porous organic polymers

T2 - Controlling the porogen size and supercritical CO2 processing

AU - Totten, Ryan K.

AU - Olenick, Laura L.

AU - Kim, Ye Seong

AU - Chakraborty, Sanjiban

AU - Weston, Mitchell H.

AU - Farha, Omar K.

AU - Hupp, Joseph T

AU - Nguyen, Sonbinh T.

PY - 2014/2

Y1 - 2014/2

N2 - Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of SnIV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO2 processing resulted in excellent enhancements of the total pore volumes.

AB - Porous organic polymers (POPs) with tunable pore volumes and surface areas can be made from a series of SnIV(porphyrins) functionalized with labile, bulky trans-diaxial ligands. Varying the ligand size allows for the tuning of the micropore volume while supercritical CO2 processing resulted in excellent enhancements of the total pore volumes.

UR - http://www.scopus.com/inward/record.url?scp=84891417214&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84891417214&partnerID=8YFLogxK

U2 - 10.1039/c3sc52010b

DO - 10.1039/c3sc52010b

M3 - Article

VL - 5

SP - 782

EP - 787

JO - Chemical Science

JF - Chemical Science

SN - 2041-6520

IS - 2

ER -