A Family of Highly Efficient CuI-Based Lighting Phosphors Prepared by a Systematic, Bottom-up Synthetic Approach

Wei Liu, Yang Fang, George Z. Wei, Simon J. Teat, Kecai Xiong, Zhichao Hu, William P. Lustig, Jing Li

Research output: Contribution to journalArticle

80 Citations (Scopus)

Abstract

Copper(I) iodide (CuI)-based inorganic-organic hybrid materials in the general chemical formula of CuI(L) are well-known for their structural diversity and strong photoluminescence and are therefore considered promising candidates for a number of optical applications. In this work, we demonstrate a systematic, bottom-up precursor approach to developing a series of CuI(L) network structures built on CuI rhomboid dimers. These compounds combine strong luminescence due to the CuI inorganic modules and significantly enhanced thermal stability as a result of connecting individual building units into robust, extended networks. Examination of their optical properties reveals that these materials not only exhibit exceptionally high photoluminescence performance (with internal quantum yield up to 95%) but also that their emission energy and color are systematically tunable through modification of the organic component. Results from density functional theory calculations provide convincing correlations between these materials' crystal structures and chemical compositions and their optophysical properties. The advantages of cost-effective, solution-processable, easily scalable and fully controllable synthesis as well as high quantum efficiency with improved thermal stability, make this phosphor family a promising candidate for alternative, RE-free phosphors in general lighting and illumination. This solution-based precursor approach creates a new blueprint for the rational design and controlled synthesis of inorganic-organic hybrid materials. (Figure Presented).

Original languageEnglish
Pages (from-to)9400-9408
Number of pages9
JournalJournal of the American Chemical Society
Volume137
Issue number29
DOIs
Publication statusPublished - Jul 29 2015

Fingerprint

Synthetic Chemistry Techniques
Hybrid materials
Lighting
Phosphors
Photoluminescence
Thermodynamic stability
Hot Temperature
Blueprints
Quantum yield
Luminescence
Quantum efficiency
Dimers
Density functional theory
Optical properties
Color
Crystal structure
Copper
Costs and Cost Analysis
Chemical analysis
Costs

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

A Family of Highly Efficient CuI-Based Lighting Phosphors Prepared by a Systematic, Bottom-up Synthetic Approach. / Liu, Wei; Fang, Yang; Wei, George Z.; Teat, Simon J.; Xiong, Kecai; Hu, Zhichao; Lustig, William P.; Li, Jing.

In: Journal of the American Chemical Society, Vol. 137, No. 29, 29.07.2015, p. 9400-9408.

Research output: Contribution to journalArticle

Liu, Wei ; Fang, Yang ; Wei, George Z. ; Teat, Simon J. ; Xiong, Kecai ; Hu, Zhichao ; Lustig, William P. ; Li, Jing. / A Family of Highly Efficient CuI-Based Lighting Phosphors Prepared by a Systematic, Bottom-up Synthetic Approach. In: Journal of the American Chemical Society. 2015 ; Vol. 137, No. 29. pp. 9400-9408.
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