A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions

Nicholas J. Schoenfeldt, Andrew W. Korinda, Justin M Notestein

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7- triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.

Original languageEnglish
Pages (from-to)1640-1642
Number of pages3
JournalChemical Communications
Volume46
Issue number10
DOIs
Publication statusPublished - 2010

Fingerprint

Oxidation
Catalysts
Manganese
Carboxylic Acids
Carboxylic acids
triazacyclononane
1,4,7-trimethyl-1,4,7-triazacyclononane

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions. / Schoenfeldt, Nicholas J.; Korinda, Andrew W.; Notestein, Justin M.

In: Chemical Communications, Vol. 46, No. 10, 2010, p. 1640-1642.

Research output: Contribution to journalArticle

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