A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry

Paul J. Toscano, Tobin J. Marks

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Abstract

13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

Original languageEnglish
Pages (from-to)400-402
Number of pages3
JournalOrganometallics
Volume5
Issue number2
DOIs
Publication statusPublished - Jan 1 1986

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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