Abstract
13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.
| Original language | English |
|---|---|
| Pages (from-to) | 400-402 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 5 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 1 1986 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Toscano, P. J., & Marks, T. J. (1986). A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry. Organometallics, 5(2), 400-402. https://doi.org/10.1021/om00133a042