A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry

Paul J. Toscano; Tobin J. Marks

doi:10.1021/om00133a042

A High-Resolution Solid-State ₁₃C NMR Study of Fe(C₅H₅)(CO)₂CH₃/Alumina Surface Chemistry

Paul J. Toscano, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

₁₃C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

Original language	English
Pages (from-to)	400-402
Number of pages	3
Journal	Organometallics
Volume	5
Issue number	2
DOIs	https://doi.org/10.1021/om00133a042
Publication status	Published - Jan 1 1986

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Access to Document

10.1021/om00133a042

Fingerprint Dive into the research topics of 'A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry'. Together they form a unique fingerprint.

Cite this

@article{0cdfb99fe26a4510b5fcd947879fe8ba,

title = "A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry",

abstract = "13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.",

author = "Toscano, {Paul J.} and Marks, {Tobin J.}",

year = "1986",

month = jan,

day = "1",

doi = "10.1021/om00133a042",

language = "English",

volume = "5",

pages = "400--402",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry

AU - Toscano, Paul J.

AU - Marks, Tobin J.

PY - 1986/1/1

Y1 - 1986/1/1

N2 - 13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

AB - 13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

UR - http://www.scopus.com/inward/record.url?scp=3843082901&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=3843082901&partnerID=8YFLogxK

U2 - 10.1021/om00133a042

DO - 10.1021/om00133a042

M3 - Article

AN - SCOPUS:3843082901

VL - 5

SP - 400

EP - 402

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 2

ER -

A High-Resolution Solid-State ₁₃C NMR Study of Fe(C₅H₅)(CO)₂CH₃/Alumina Surface Chemistry

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint Dive into the research topics of 'A High-Resolution Solid-State <sub>13</sub>C NMR Study of Fe(C<sub>5</sub>H<sub>5</sub>)(CO)<sub>2</sub>CH<sub>3</sub>/Alumina Surface Chemistry'. Together they form a unique fingerprint.

Cite this