A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry

Paul J. Toscano; Tobin J. Marks

doi:10.1021/om00133a042

A High-Resolution Solid-State ₁₃C NMR Study of Fe(C₅H₅)(CO)₂CH₃/Alumina Surface Chemistry

Paul J. Toscano, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

₁₃C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

Original language	English
Pages (from-to)	400-402
Number of pages	3
Journal	Organometallics
Volume	5
Issue number	2
DOIs	https://doi.org/10.1021/om00133a042
Publication status	Published - Jan 1 1986

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.",

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N2 - 13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

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