Abstract
13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes (Cp = and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.
Original language | English |
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Pages (from-to) | 400-402 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 5 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jan 1 1986 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry