A high-resolution solid-state 13C NMR study of Fe(C5H5)(CO)2CH3/alumina surface chemistry

Paul J. Toscano, Tobin J Marks

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

13C CPMAS NMR spectroscopy has been employed to characterize surface reaction pathways involving the complexes CpFe(CO)2CH3, CpFe(13CO)2CH3, CpFe(CO)2(13CH3) (Cp = η5-C5H5), and dehydroxylated (DA) or partially dehydroxylated (PDA) γ-alumina. A number of possible reaction modes can be ruled out, and surface-induced migratory CO insertion to yield a carbene-like acyl complex is identified as the predominant if not exclusive pathway.

Original languageEnglish
Pages (from-to)400-402
Number of pages3
JournalOrganometallics
Volume5
Issue number2
Publication statusPublished - 1986

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Aluminum Oxide
carbenes
Carbon Monoxide
Surface chemistry
surface reactions
insertion
aluminum oxides
Nuclear magnetic resonance
chemistry
solid state
nuclear magnetic resonance
high resolution
spectroscopy
Surface reactions
Nuclear magnetic resonance spectroscopy

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

A high-resolution solid-state 13C NMR study of Fe(C5H5)(CO)2CH3/alumina surface chemistry. / Toscano, Paul J.; Marks, Tobin J.

In: Organometallics, Vol. 5, No. 2, 1986, p. 400-402.

Research output: Contribution to journalArticle

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