A mercurial route to a cobalt dihydrogen complex

R. Morris Bullock

doi:10.1002/anie.201006731

A mercurial route to a cobalt dihydrogen complex

R. Morris Bullock

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H₂ gives a rare dihydrogen complex of cobalt, and a second H₂ molecule is added at higher pressures and low temperature (see scheme).

Original language	English
Pages (from-to)	4050-4052
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	18
DOIs	https://doi.org/10.1002/anie.201006731
Publication status	Published - Apr 26 2011

Keywords

NMR spectroscopy
cobalt
dihydrogen
hydride ligands
mercury

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.201006731

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abstract = "Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H2 gives a rare dihydrogen complex of cobalt, and a second H2 molecule is added at higher pressures and low temperature (see scheme).",

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KW - dihydrogen

KW - hydride ligands

KW - mercury

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