Abstract
Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H2 gives a rare dihydrogen complex of cobalt, and a second H2 molecule is added at higher pressures and low temperature (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 4050-4052 |
| Number of pages | 3 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 50 |
| Issue number | 18 |
| DOIs | |
| Publication status | Published - Apr 26 2011 |
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Keywords
- cobalt
- dihydrogen
- hydride ligands
- mercury
- NMR spectroscopy
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
A mercurial route to a cobalt dihydrogen complex. / Bullock, R Morris.
In: Angewandte Chemie - International Edition, Vol. 50, No. 18, 26.04.2011, p. 4050-4052.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A mercurial route to a cobalt dihydrogen complex
AU - Bullock, R Morris
PY - 2011/4/26
Y1 - 2011/4/26
N2 - Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H2 gives a rare dihydrogen complex of cobalt, and a second H2 molecule is added at higher pressures and low temperature (see scheme).
AB - Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H2 gives a rare dihydrogen complex of cobalt, and a second H2 molecule is added at higher pressures and low temperature (see scheme).
KW - cobalt
KW - dihydrogen
KW - hydride ligands
KW - mercury
KW - NMR spectroscopy
UR - http://www.scopus.com/inward/record.url?scp=79955440891&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79955440891&partnerID=8YFLogxK
U2 - 10.1002/anie.201006731
DO - 10.1002/anie.201006731
M3 - Article
VL - 50
SP - 4050
EP - 4052
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 18
ER -