A mercurial route to a cobalt dihydrogen complex

R Morris Bullock

doi:10.1002/anie.201006731

A mercurial route to a cobalt dihydrogen complex

R Morris Bullock

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

3 Citations (Scopus)

Abstract

Mercury for protection? Mercury protects the highly reactive 14-electron {Co(POCOP)} fragment in a Co-Hg-Co complex, but reaction with H₂ gives a rare dihydrogen complex of cobalt, and a second H₂ molecule is added at higher pressures and low temperature (see scheme).

Original language	English
Pages (from-to)	4050-4052
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	18
DOIs	https://doi.org/10.1002/anie.201006731
Publication status	Published - Apr 26 2011

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Keywords

cobalt
dihydrogen
hydride ligands
mercury
NMR spectroscopy

ASJC Scopus subject areas

Chemistry(all)
Catalysis

Cite this

Bullock, R. M. (2011). A mercurial route to a cobalt dihydrogen complex. Angewandte Chemie - International Edition, 50(18), 4050-4052. https://doi.org/10.1002/anie.201006731

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Access to Document

10.1002/anie.201006731