A metal-organic framework immobilised iridium pincer complex

Martino Rimoldi, Akitake Nakamura, Nicolaas A. Vermeulen, James J. Henkelis, Anthea K. Blackburn, Joseph T Hupp, J. Fraser Stoddart, Omar K. Farha

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

An iridium pincer complex has been immobilised in the metal-organic framework NU-1000 using a technique called solvent assisted ligand-incorporation (SALI). The framework proved to be stable under the conditions required to activate the iridium complex and spectroscopic investigations showed formation of the catalytically active iridium dihydride. The Ir-pincer modified NU-1000 is an active catalyst for the condensed phase hydrogenation of a liquid alkene (1-decene and styrene) and shows enhanced activity with respect to a homogeneous analogue. Additionally, the Ir-pincer immobilised inside NU-1000 operated as an efficient heterogenous catalyst under flow conditions.

Original languageEnglish
Pages (from-to)4980-4984
Number of pages5
JournalChemical Science
Volume7
Issue number8
DOIs
Publication statusPublished - 2016

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Iridium
Metals
Catalysts
Styrene
Alkenes
Hydrogenation
Ligands
Liquids

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Rimoldi, M., Nakamura, A., Vermeulen, N. A., Henkelis, J. J., Blackburn, A. K., Hupp, J. T., ... Farha, O. K. (2016). A metal-organic framework immobilised iridium pincer complex. Chemical Science, 7(8), 4980-4984. https://doi.org/10.1039/c6sc01376g

A metal-organic framework immobilised iridium pincer complex. / Rimoldi, Martino; Nakamura, Akitake; Vermeulen, Nicolaas A.; Henkelis, James J.; Blackburn, Anthea K.; Hupp, Joseph T; Stoddart, J. Fraser; Farha, Omar K.

In: Chemical Science, Vol. 7, No. 8, 2016, p. 4980-4984.

Research output: Contribution to journalArticle

Rimoldi, M, Nakamura, A, Vermeulen, NA, Henkelis, JJ, Blackburn, AK, Hupp, JT, Stoddart, JF & Farha, OK 2016, 'A metal-organic framework immobilised iridium pincer complex', Chemical Science, vol. 7, no. 8, pp. 4980-4984. https://doi.org/10.1039/c6sc01376g
Rimoldi M, Nakamura A, Vermeulen NA, Henkelis JJ, Blackburn AK, Hupp JT et al. A metal-organic framework immobilised iridium pincer complex. Chemical Science. 2016;7(8):4980-4984. https://doi.org/10.1039/c6sc01376g
Rimoldi, Martino ; Nakamura, Akitake ; Vermeulen, Nicolaas A. ; Henkelis, James J. ; Blackburn, Anthea K. ; Hupp, Joseph T ; Stoddart, J. Fraser ; Farha, Omar K. / A metal-organic framework immobilised iridium pincer complex. In: Chemical Science. 2016 ; Vol. 7, No. 8. pp. 4980-4984.
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