A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation

So Hye Cho, Baoqing Ma, Son Binh T. Nguyen, Joseph T. Hupp, Thomas E. Albrecht-Schmitt

Research output: Contribution to journalArticle

830 Citations (Scopus)

Abstract

A new microporous metal-organic framework compound featuring chiral (salen)Mn struts is highly effective as an asymmetric catalyst for olefin epoxidation, yielding enantiomeric excesses that rival those of the free molecular analogue. Framework confinement of the manganese salen entity enhances catalyst stability, imparts substrate size selectivity, and permits catalyst separation and reuse.

Original languageEnglish
Pages (from-to)2563-2565
Number of pages3
JournalChemical Communications
Issue number24
DOIs
Publication statusPublished - Jan 1 2006

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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