A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67

Paul W. Siu, Zachary J. Brown, Omar K. Farha, Joseph T Hupp, Karl A. Scheidt

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4′- dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.

Original languageEnglish
Pages (from-to)10920-10922
Number of pages3
JournalChemical Communications
Volume49
Issue number93
DOIs
Publication statusPublished - Dec 4 2013

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Struts
Urea
Catalyst activity
Metals
Derivatives
Pore size
Hydrogen bonds
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67. / Siu, Paul W.; Brown, Zachary J.; Farha, Omar K.; Hupp, Joseph T; Scheidt, Karl A.

In: Chemical Communications, Vol. 49, No. 93, 04.12.2013, p. 10920-10922.

Research output: Contribution to journalArticle

Siu, Paul W. ; Brown, Zachary J. ; Farha, Omar K. ; Hupp, Joseph T ; Scheidt, Karl A. / A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67. In: Chemical Communications. 2013 ; Vol. 49, No. 93. pp. 10920-10922.
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