Abstract
A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4’-dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.
| Original language | English |
|---|---|
| Pages (from-to) | 10920-10922 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 93 |
| DOIs | |
| Publication status | Published - Oct 29 2013 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Siu, P. W., Brown, Z. J., Farha, O. K., Hupp, J. T., & Scheidt, K. A. (2013). A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67. Chemical Communications, 49(93), 10920-10922. https://doi.org/10.1039/c3cc47177b