Abstract
A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4′- dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.
| Original language | English |
|---|---|
| Pages (from-to) | 10920-10922 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 49 |
| Issue number | 93 |
| DOIs | |
| Publication status | Published - Dec 4 2013 |
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ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Surfaces, Coatings and Films
- Materials Chemistry
- Metals and Alloys
Cite this
A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67. / Siu, Paul W.; Brown, Zachary J.; Farha, Omar K.; Hupp, Joseph T; Scheidt, Karl A.
In: Chemical Communications, Vol. 49, No. 93, 04.12.2013, p. 10920-10922.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal-organic framework UiO-67
AU - Siu, Paul W.
AU - Brown, Zachary J.
AU - Farha, Omar K.
AU - Hupp, Joseph T
AU - Scheidt, Karl A.
PY - 2013/12/4
Y1 - 2013/12/4
N2 - A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4′- dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.
AB - A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4′- dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.
UR - http://www.scopus.com/inward/record.url?scp=84886825721&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84886825721&partnerID=8YFLogxK
U2 - 10.1039/c3cc47177b
DO - 10.1039/c3cc47177b
M3 - Article
VL - 49
SP - 10920
EP - 10922
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 93
ER -