A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67

Paul W. Siu; Zachary J. Brown; Omar K. Farha; Joseph T. Hupp; Karl A. Scheidt

doi:10.1039/c3cc47177b

A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67

Paul W. Siu, Zachary J. Brown, Omar K. Farha, Joseph T. Hupp, Karl A. Scheidt

Northwestern University

Research output: Contribution to journal › Article

64 Citations (Scopus)

Abstract

A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4’-dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.

Original language	English
Pages (from-to)	10920-10922
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	93
DOIs	https://doi.org/10.1039/c3cc47177b
Publication status	Published - Oct 29 2013

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Siu, P. W., Brown, Z. J., Farha, O. K., Hupp, J. T., & Scheidt, K. A. (2013). A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67. Chemical Communications, 49(93), 10920-10922. https://doi.org/10.1039/c3cc47177b

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10.1039/c3cc47177b