A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67

Paul W. Siu; Zachary J. Brown; Omar K. Farha; Joseph T. Hupp; Karl A. Scheidt

doi:10.1039/c3cc47177b

A mixed dicarboxylate strut approach to enhancing catalytic activity of a de novo urea derivative of metal–organic framework UiO-67

Paul W. Siu, Zachary J. Brown, Omar K. Farha, Joseph T. Hupp, Karl A. Scheidt

Northwestern University

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4’-dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.

Original language	English
Pages (from-to)	10920-10922
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	93
DOIs	https://doi.org/10.1039/c3cc47177b
Publication status	Published - Oct 29 2013

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "A hydrogen-bond donating MOF catalyst based on the UiO-67 framework, containing both urea-functionalized dicarboxylate and biphenyl-4,4{\textquoteright}-dicarboxylate struts, was synthesized by a de novo route. The mixed strut framework has larger pore sizes and improved catalytic activity for Henry reactions than the pure strut analogue, which contains only the urea-functionalized dicarboxylate linker.",

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AU - Scheidt, Karl A.

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