Abstract
A monolithically integrated device consisting of a tandem-junction GaAs/InGaP photoanode coated by an amorphous TiO2 stabilization layer, in conjunction with Ni-based, earth-abundant active electrocatalysts for the hydrogen-evolution and oxygen-evolution reactions, was used to effect unassisted, solar-driven water splitting in 1.0 M KOH(aq). When connected to a Ni-Mo-coated counterelectrode in a two-electrode cell configuration, the TiO2-protected III-V tandem device exhibited a solar-to-hydrogen conversion efficiency, ηSTH, of 10.5% under 1 sun illumination, with stable performance for >40 h of continuous operation at an efficiency of ηSTH > 10%. The protected tandem device also formed the basis for a monolithically integrated, intrinsically safe solar-hydrogen prototype system (1 cm2) driven by a NiMo/GaAs/InGaP/TiO2/Ni structure. The intrinsically safe system exhibited a hydrogen production rate of 0.81 μL s-1 and a solar-to-hydrogen conversion efficiency of 8.6% under 1 sun illumination in 1.0 M KOH(aq), with minimal product gas crossover while allowing for beneficial collection of separate streams of H2(g) and O2(g).
| Original language | English |
|---|---|
| Pages (from-to) | 3166-3172 |
| Number of pages | 7 |
| Journal | Energy and Environmental Science |
| Volume | 8 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - Nov 1 2015 |
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ASJC Scopus subject areas
- Renewable Energy, Sustainability and the Environment
- Environmental Chemistry
- Pollution
- Nuclear Energy and Engineering
Cite this
A monolithically integrated, intrinsically safe, 10% efficient, solar-driven water-splitting system based on active, stable earth-abundant electrocatalysts in conjunction with tandem III-V light absorbers protected by amorphous TiO2 films. / Verlage, Erik; Hu, Shu; Liu, Rui; Jones, Ryan J R; Sun, Ke; Xiang, Chengxiang; Lewis, Nathan S; Atwater, Harry A.
In: Energy and Environmental Science, Vol. 8, No. 11, 01.11.2015, p. 3166-3172.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A monolithically integrated, intrinsically safe, 10% efficient, solar-driven water-splitting system based on active, stable earth-abundant electrocatalysts in conjunction with tandem III-V light absorbers protected by amorphous TiO2 films
AU - Verlage, Erik
AU - Hu, Shu
AU - Liu, Rui
AU - Jones, Ryan J R
AU - Sun, Ke
AU - Xiang, Chengxiang
AU - Lewis, Nathan S
AU - Atwater, Harry A.
PY - 2015/11/1
Y1 - 2015/11/1
N2 - A monolithically integrated device consisting of a tandem-junction GaAs/InGaP photoanode coated by an amorphous TiO2 stabilization layer, in conjunction with Ni-based, earth-abundant active electrocatalysts for the hydrogen-evolution and oxygen-evolution reactions, was used to effect unassisted, solar-driven water splitting in 1.0 M KOH(aq). When connected to a Ni-Mo-coated counterelectrode in a two-electrode cell configuration, the TiO2-protected III-V tandem device exhibited a solar-to-hydrogen conversion efficiency, ηSTH, of 10.5% under 1 sun illumination, with stable performance for >40 h of continuous operation at an efficiency of ηSTH > 10%. The protected tandem device also formed the basis for a monolithically integrated, intrinsically safe solar-hydrogen prototype system (1 cm2) driven by a NiMo/GaAs/InGaP/TiO2/Ni structure. The intrinsically safe system exhibited a hydrogen production rate of 0.81 μL s-1 and a solar-to-hydrogen conversion efficiency of 8.6% under 1 sun illumination in 1.0 M KOH(aq), with minimal product gas crossover while allowing for beneficial collection of separate streams of H2(g) and O2(g).
AB - A monolithically integrated device consisting of a tandem-junction GaAs/InGaP photoanode coated by an amorphous TiO2 stabilization layer, in conjunction with Ni-based, earth-abundant active electrocatalysts for the hydrogen-evolution and oxygen-evolution reactions, was used to effect unassisted, solar-driven water splitting in 1.0 M KOH(aq). When connected to a Ni-Mo-coated counterelectrode in a two-electrode cell configuration, the TiO2-protected III-V tandem device exhibited a solar-to-hydrogen conversion efficiency, ηSTH, of 10.5% under 1 sun illumination, with stable performance for >40 h of continuous operation at an efficiency of ηSTH > 10%. The protected tandem device also formed the basis for a monolithically integrated, intrinsically safe solar-hydrogen prototype system (1 cm2) driven by a NiMo/GaAs/InGaP/TiO2/Ni structure. The intrinsically safe system exhibited a hydrogen production rate of 0.81 μL s-1 and a solar-to-hydrogen conversion efficiency of 8.6% under 1 sun illumination in 1.0 M KOH(aq), with minimal product gas crossover while allowing for beneficial collection of separate streams of H2(g) and O2(g).
UR - http://www.scopus.com/inward/record.url?scp=84946137738&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84946137738&partnerID=8YFLogxK
U2 - 10.1039/c5ee01786f
DO - 10.1039/c5ee01786f
M3 - Article
AN - SCOPUS:84946137738
VL - 8
SP - 3166
EP - 3172
JO - Energy and Environmental Science
JF - Energy and Environmental Science
SN - 1754-5692
IS - 11
ER -