A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes

Carole Duboc, Vincent Astier-Perret, Hongyu Chen, Jacques Pécaut, Robert H. Crabtree, Gary W Brudvig, Marie Noëlle Collomb

Research output: Contribution to journal › Article

34 Citations (Scopus)

Abstract

The electronic structure of a series of 11 penta-coordinated dichloride mononuclear Mn(II) complexes [Mn(L)Cl2] (L = Cl-terpy, Br-terpy, OH-terpy, phenyl-terpy, tolyl-terpy, mesityl-terpy, EtO-terpy, Me 2N-terpy, tBu3-terpy, py-phen, and dpya) has been investigated by a multifrequency EPR study (9-285 GHz). The X-ray structures of [Mn(Br-terpy)Cl2], [Mn(EtO-terpy)Cl2], [Mn(Me 2N-terpy)Cl2] and [Mn(tolyl-terpy)Cl2] are described. The spin Hamiltonian parameters have been determined for all complexes and show that the steric and electronic effects of the N-tridentate ligand L do not induce appreciable variations on the zero field splitting parameters. The magnitude of D, close to 0.3 cm-1, is governed by the chloride anion. High-field EPR spectroscopy allows the determination of electronic parameters of mononuclear Mn(II) complexes characterized by relatively large magnitudes of D and the unambiguous interpretation of the X-band spectra of these kinds of complexes.

Original languageEnglish
Pages (from-to)1541-1548
Number of pages8
JournalInorganica Chimica Acta
Volume359
Issue number5
DOIs
Publication statusPublished - Mar 20 2006

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Rubiaceae
dichlorides
Anions
Paramagnetic resonance
Chlorides
Spectrum Analysis
X-Rays
Ligands
Hamiltonians
Electronic structure
Negative ions
Spectroscopy
superhigh frequencies
electronics
X rays
chlorides
electronic structure
anions
ligands
spectroscopy

Keywords

  • Electronic properties
  • High field EPR
  • Mononuclear dichloro-manganese(II) complex
  • Multifrequency EPR spectroscopy
  • N-Tridentate ligand

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes. / Duboc, Carole; Astier-Perret, Vincent; Chen, Hongyu; Pécaut, Jacques; Crabtree, Robert H.; Brudvig, Gary W; Collomb, Marie Noëlle.

In: Inorganica Chimica Acta, Vol. 359, No. 5, 20.03.2006, p. 1541-1548.

Research output: Contribution to journal › Article

Duboc, C, Astier-Perret, V, Chen, H, Pécaut, J, Crabtree, RH, Brudvig, GW & Collomb, MN 2006, 'A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes', Inorganica Chimica Acta, vol. 359, no. 5, pp. 1541-1548. https://doi.org/10.1016/j.ica.2005.10.027
Duboc C, Astier-Perret V, Chen H, Pécaut J, Crabtree RH, Brudvig GW et al. A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes. Inorganica Chimica Acta. 2006 Mar 20;359(5):1541-1548. https://doi.org/10.1016/j.ica.2005.10.027
Duboc, Carole ; Astier-Perret, Vincent ; Chen, Hongyu ; Pécaut, Jacques ; Crabtree, Robert H. ; Brudvig, Gary W ; Collomb, Marie Noëlle. / A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes. In: Inorganica Chimica Acta. 2006 ; Vol. 359, No. 5. pp. 1541-1548.
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AB - The electronic structure of a series of 11 penta-coordinated dichloride mononuclear Mn(II) complexes [Mn(L)Cl2] (L = Cl-terpy, Br-terpy, OH-terpy, phenyl-terpy, tolyl-terpy, mesityl-terpy, EtO-terpy, Me 2N-terpy, tBu3-terpy, py-phen, and dpya) has been investigated by a multifrequency EPR study (9-285 GHz). The X-ray structures of [Mn(Br-terpy)Cl2], [Mn(EtO-terpy)Cl2], [Mn(Me 2N-terpy)Cl2] and [Mn(tolyl-terpy)Cl2] are described. The spin Hamiltonian parameters have been determined for all complexes and show that the steric and electronic effects of the N-tridentate ligand L do not induce appreciable variations on the zero field splitting parameters. The magnitude of D, close to 0.3 cm-1, is governed by the chloride anion. High-field EPR spectroscopy allows the determination of electronic parameters of mononuclear Mn(II) complexes characterized by relatively large magnitudes of D and the unambiguous interpretation of the X-band spectra of these kinds of complexes.

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