A naphthodithiophene-diketopyrrolopyrrole donor molecule for efficient solution-processed solar cells

Stephen Loser, Carson J. Bruns, Hiroyuki Miyauchi, Rocío Ponce Ortiz, Antonio Facchetti, Samuel I. Stupp, Tobin J. Marks

Research output: Contribution to journalArticle

444 Citations (Scopus)

Abstract

We report the synthesis, characterization, and first implementation of a naphtho[2,3-b:6,7-b′]dithiophene (NDT)-based donor molecule in highly efficient organic photovoltaics (OPVs). When NDT(TDPP) 2 (TDPP = thiophene-capped diketopyrrolopyrrole) is combined with the electron acceptor PC 61BM, a power conversion efficiency (PCE) of 4.06 ± 0.06% is achieved - a record for a PC 61BM-based small-molecule OPV. The substantial PCE is attributed to the broad, high oscillator strength visible absorption, the ordered molecular packing, and an exceptional hole mobility of NDT(TDPP) 2.

Original languageEnglish
Pages (from-to)8142-8145
Number of pages4
JournalJournal of the American Chemical Society
Volume133
Issue number21
DOIs
Publication statusPublished - Jun 1 2011

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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