A Neutrally Charged Trimethylmanganese(III) Complex: Synthesis, Characterization, and Disproportionation Chemistry

Madelyn M. Stalzer, Joshua Telser, Jurek Krzystek, Alessandro Motta, Massimiliano Delferro, Tobin J Marks

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The synthesis and properties of an unusual, neutrally charged and volatile N,N,N′,N′-tetramethylethylenediamine trimethyl manganese(III) complex, (TMEDA)MnMe3, are described, along with its facile disproportionation to the corresponding Mn(II) and Mn(IV) complexes. Characterization by single-crystal XRD, UV-vis spectroscopy, high-frequency and -field EPR (HFEPR), magnetic susceptibility, and density functional theory (DFT) computations indicate that the (TMEDA)MnMe3 electronic structure can be described as largely square pyramidal Mn(III) centered. The paucity of manganese(III) polyalkyls and the simplicity and reactivity of this compound implicate it as a potentially useful synthetic building block.

Original languageEnglish
Pages (from-to)2683-2688
Number of pages6
JournalOrganometallics
Volume35
Issue number16
DOIs
Publication statusPublished - Aug 22 2016

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synthesis (chemistry)
Manganese
manganese
chemistry
Ultraviolet spectroscopy
Magnetic susceptibility
Electronic structure
Density functional theory
Paramagnetic resonance
reactivity
Single crystals
density functional theory
electronic structure
magnetic permeability
single crystals
synthesis
spectroscopy
N,N,N',N'-tetramethylethylenediamine

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

A Neutrally Charged Trimethylmanganese(III) Complex : Synthesis, Characterization, and Disproportionation Chemistry. / Stalzer, Madelyn M.; Telser, Joshua; Krzystek, Jurek; Motta, Alessandro; Delferro, Massimiliano; Marks, Tobin J.

In: Organometallics, Vol. 35, No. 16, 22.08.2016, p. 2683-2688.

Research output: Contribution to journalArticle

Stalzer, Madelyn M. ; Telser, Joshua ; Krzystek, Jurek ; Motta, Alessandro ; Delferro, Massimiliano ; Marks, Tobin J. / A Neutrally Charged Trimethylmanganese(III) Complex : Synthesis, Characterization, and Disproportionation Chemistry. In: Organometallics. 2016 ; Vol. 35, No. 16. pp. 2683-2688.
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