Abstract
A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.
| Original language | English |
|---|---|
| Pages (from-to) | 102-107 |
| Number of pages | 6 |
| Journal | Journal of Magnetic Resonance, Series A |
| Volume | 113 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Mar 1995 |
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ASJC Scopus subject areas
- Engineering(all)
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A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids. / Yonker, C. R.; Zemanian, T. S.; Wallen, S. L.; Linehan, John; Franz, J. A.
In: Journal of Magnetic Resonance, Series A, Vol. 113, No. 1, 03.1995, p. 102-107.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids
AU - Yonker, C. R.
AU - Zemanian, T. S.
AU - Wallen, S. L.
AU - Linehan, John
AU - Franz, J. A.
PY - 1995/3
Y1 - 1995/3
N2 - A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.
AB - A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.
UR - http://www.scopus.com/inward/record.url?scp=0000060915&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000060915&partnerID=8YFLogxK
U2 - 10.1006/jmra.1995.1061
DO - 10.1006/jmra.1995.1061
M3 - Article
AN - SCOPUS:0000060915
VL - 113
SP - 102
EP - 107
JO - Journal of Magnetic Resonance
JF - Journal of Magnetic Resonance
SN - 1090-7807
IS - 1
ER -