A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids

C. R. Yonker, T. S. Zemanian, S. L. Wallen, John Linehan, J. A. Franz

Research output: Contribution to journalArticle

47 Citations (Scopus)

Abstract

A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.

Original languageEnglish
Pages (from-to)102-107
Number of pages6
JournalJournal of Magnetic Resonance, Series A
Volume113
Issue number1
DOIs
Publication statusPublished - Mar 1995

Fingerprint

Capillary Tubing
Nuclear magnetic resonance
Pressure
nuclear magnetic resonance
Liquids
Tubing
liquids
cells
Supercritical fluids
Explosions
supercritical fluids
Organometallics
Fused silica
Silicon Dioxide
hazards
explosions
Hazards
chambers
Observation
tubes

ASJC Scopus subject areas

  • Engineering(all)

Cite this

A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids. / Yonker, C. R.; Zemanian, T. S.; Wallen, S. L.; Linehan, John; Franz, J. A.

In: Journal of Magnetic Resonance, Series A, Vol. 113, No. 1, 03.1995, p. 102-107.

Research output: Contribution to journalArticle

Yonker, C. R. ; Zemanian, T. S. ; Wallen, S. L. ; Linehan, John ; Franz, J. A. / A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids. In: Journal of Magnetic Resonance, Series A. 1995 ; Vol. 113, No. 1. pp. 102-107.
@article{ae159184b624461bb2dffb2a52ce49e3,
title = "A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids",
abstract = "A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.",
author = "Yonker, {C. R.} and Zemanian, {T. S.} and Wallen, {S. L.} and John Linehan and Franz, {J. A.}",
year = "1995",
month = "3",
doi = "10.1006/jmra.1995.1061",
language = "English",
volume = "113",
pages = "102--107",
journal = "Journal of Magnetic Resonance",
issn = "1090-7807",
publisher = "Academic Press Inc.",
number = "1",

}

TY - JOUR

T1 - A New Apparatus for the Convenient Measurement of NMR Spectra in High-Pressure Liquids

AU - Yonker, C. R.

AU - Zemanian, T. S.

AU - Wallen, S. L.

AU - Linehan, John

AU - Franz, J. A.

PY - 1995/3

Y1 - 1995/3

N2 - A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.

AB - A novel design is presented for a high-pressure NMR cell using fused silica capillary tubing. The capillary tubing is bent to form multiple loops for use in a 5 mm NMR tube in a conventional solution NMR probe. The NMR cell design eliminates explosion hazards at high pressures and makes possible simple sample loading and observation of reaction mixtures at variable pressures (up to 4 kbar) and temperatures. A chamber for the mixing and flow introduction of reaction mixtures is provided. Examples of application of the cell for 1H, 129Xe, and 19F studies of supercritical fluids, near-critical liquids, and high-pressure organometallic reactions are presented.

UR - http://www.scopus.com/inward/record.url?scp=0000060915&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000060915&partnerID=8YFLogxK

U2 - 10.1006/jmra.1995.1061

DO - 10.1006/jmra.1995.1061

M3 - Article

VL - 113

SP - 102

EP - 107

JO - Journal of Magnetic Resonance

JF - Journal of Magnetic Resonance

SN - 1090-7807

IS - 1

ER -