A new method for the synthesis of organopolyoxometalate hybrid compounds

Itsik Bar-Nahum, Jessica Ettedgui, Leonid Konstantinovski, Vladimir Kogan, Ronny Neumann

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The reaction of a quaternary ammonium salt of the tin chloride-substituted polyoxometalate, [PSn(Cl)W11O39]4-, with a variety of n-nucleophiles including primary, secondary, and tertiary amines and a tertiary phosphine, yielded tin-centered Lewis acid-base adducts, [PSn(Cl)W11O39]4--n-nucleophile; with more nucleophilic secondary amines such as diisopropylamine, apparently some [PSnN[CH(CH3)2]2W11O 39]4- was formed as a minor product. The compounds were identified by 1H, 119Sn, 15N, 31P, and 183W NMR, ESI-MS, and elemental analyses. The key connectivity of the Sn-Cl center with the amine was clarified by the observation of 3J Sn-H couplings (Sn from the polyoxometalate cluster and H from the amine moiety) in a 2D 119Sn-1H heteronuclear multiple-bond correlation NMR experiment. This new, rather simple synthetic method was also utilized for preparing amino acid-polyoxometalate hybrid compounds.

Original languageEnglish
Pages (from-to)5798-5804
Number of pages7
JournalInorganic Chemistry
Volume46
Issue number14
DOIs
Publication statusPublished - Jul 9 2007

    Fingerprint

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this