A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature

Matthias Vogt, Moti Gargir, Mark A. Iron, Yael Diskin-Posner, Yehoshoa Ben-David, David Milstein

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

Team work: Although CO2 binding to metal centers usually involves π coordination to a Cï£O group or Ï bonds to the carbon or oxygen atom of the CO2 molecule, a new mode of metal-ligand cooperative activation of CO2 to a ruthenium PNP pincer complex involving aromatization/dearomatization steps is presented in experimental and theoretical studies (see scheme).

Original languageEnglish
Pages (from-to)9194-9197
Number of pages4
JournalChemistry - A European Journal
Volume18
Issue number30
DOIs
Publication statusPublished - Jul 23 2012

Fingerprint

Metals
Chemical activation
Ligands
Aromatization
Ruthenium
Carbon Monoxide
Carbon
Oxygen
Atoms
Temperature
Molecules

Keywords

  • CO activation
  • density functional calculations
  • isotopic labeling
  • metal-ligand cooperation
  • NMR spectroscopy
  • PNP pincer ligands
  • ruthenium

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature. / Vogt, Matthias; Gargir, Moti; Iron, Mark A.; Diskin-Posner, Yael; Ben-David, Yehoshoa; Milstein, David.

In: Chemistry - A European Journal, Vol. 18, No. 30, 23.07.2012, p. 9194-9197.

Research output: Contribution to journalArticle

Vogt, Matthias ; Gargir, Moti ; Iron, Mark A. ; Diskin-Posner, Yael ; Ben-David, Yehoshoa ; Milstein, David. / A new mode of activation of CO2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature. In: Chemistry - A European Journal. 2012 ; Vol. 18, No. 30. pp. 9194-9197.
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