A new mononuclear thiolato nickel(II) square planar complex with an uncommon (S2NO) coordination

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Abstract

The synthesis, structure, spectra and properties of (Ph4P)[Ni(MSA)(SPh)] (tetraphenylphosphonium 2-(2-mercaptophenyl)salicyladiminato thiophenolato nickelate(II)) (I) are reported. The compound crystallizes as red needles in the monoclinic spaces group P21/c with cell dimensions a = 10.813(6), b = 17.061(6), c = 19.873(10) Å, β = 100.06(5)°, V = 3610(3) Å3, Z = 4. The structure was solved by conventional methods using 4919 reflections and refined to R = 5.7% and Rw = 6.6%. The complex features a square planar Ni2+ environment in which the metal center is bound to two sulfur, a nitrogen an an oxygen atom. The corresponding phenolato complex (Ph4P)[Ni(MSA)(OPh)] (II) is X-ray isomorphous to I. The electronic spectra and electrochemical properties of I and II are discussed.

Original languageEnglish
Pages (from-to)101-103
Number of pages3
JournalInorganica Chimica Acta
Volume168
Issue number1
DOIs
Publication statusPublished - Feb 1 1990

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Nickel
Electrochemical properties
Sulfur
Needles
Nitrogen
Metals
X-Rays
nickel
Oxygen
X rays
Atoms
needles
electronic spectra
oxygen atoms
sulfur
nitrogen
synthesis
cells
metals
x rays

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

A new mononuclear thiolato nickel(II) square planar complex with an uncommon (S2NO) coordination. / Kanatzidis, Mercouri G.

In: Inorganica Chimica Acta, Vol. 168, No. 1, 01.02.1990, p. 101-103.

Research output: Contribution to journalArticle

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N2 - The synthesis, structure, spectra and properties of (Ph4P)[Ni(MSA)(SPh)] (tetraphenylphosphonium 2-(2-mercaptophenyl)salicyladiminato thiophenolato nickelate(II)) (I) are reported. The compound crystallizes as red needles in the monoclinic spaces group P21/c with cell dimensions a = 10.813(6), b = 17.061(6), c = 19.873(10) Å, β = 100.06(5)°, V = 3610(3) Å3, Z = 4. The structure was solved by conventional methods using 4919 reflections and refined to R = 5.7% and Rw = 6.6%. The complex features a square planar Ni2+ environment in which the metal center is bound to two sulfur, a nitrogen an an oxygen atom. The corresponding phenolato complex (Ph4P)[Ni(MSA)(OPh)] (II) is X-ray isomorphous to I. The electronic spectra and electrochemical properties of I and II are discussed.

AB - The synthesis, structure, spectra and properties of (Ph4P)[Ni(MSA)(SPh)] (tetraphenylphosphonium 2-(2-mercaptophenyl)salicyladiminato thiophenolato nickelate(II)) (I) are reported. The compound crystallizes as red needles in the monoclinic spaces group P21/c with cell dimensions a = 10.813(6), b = 17.061(6), c = 19.873(10) Å, β = 100.06(5)°, V = 3610(3) Å3, Z = 4. The structure was solved by conventional methods using 4919 reflections and refined to R = 5.7% and Rw = 6.6%. The complex features a square planar Ni2+ environment in which the metal center is bound to two sulfur, a nitrogen an an oxygen atom. The corresponding phenolato complex (Ph4P)[Ni(MSA)(OPh)] (II) is X-ray isomorphous to I. The electronic spectra and electrochemical properties of I and II are discussed.

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