A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]

L. V. Zorina, S. S. Khasanov, R. P. Shibaeva, M. Gener, Roger Rousseau, E. Canadell, L. A. Kushch, E. B. Yagubskii, O. O. Drozdova, K. Yakushi

Research output: Contribution to journalArticle

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Abstract

(BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) Å, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) Å3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.

Original languageEnglish
Pages (from-to)2017-2023
Number of pages7
JournalJournal of Materials Chemistry
Volume10
Issue number9
DOIs
Publication statusPublished - 2000

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Nitroprusside
Anions
Negative ions
Salts
Metals
anions
salts
Helium
Fermi surface
liquid helium
Stoichiometry
Band structure
metals
Electrolytes
Fermi surfaces
Cations
stoichiometry
Crystal structure
Positive ions
electrolytes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Materials Chemistry
  • Materials Science(all)

Cite this

A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]. / Zorina, L. V.; Khasanov, S. S.; Shibaeva, R. P.; Gener, M.; Rousseau, Roger; Canadell, E.; Kushch, L. A.; Yagubskii, E. B.; Drozdova, O. O.; Yakushi, K.

In: Journal of Materials Chemistry, Vol. 10, No. 9, 2000, p. 2017-2023.

Research output: Contribution to journalArticle

Zorina, LV, Khasanov, SS, Shibaeva, RP, Gener, M, Rousseau, R, Canadell, E, Kushch, LA, Yagubskii, EB, Drozdova, OO & Yakushi, K 2000, 'A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]', Journal of Materials Chemistry, vol. 10, no. 9, pp. 2017-2023. https://doi.org/10.1039/b003433i
Zorina, L. V. ; Khasanov, S. S. ; Shibaeva, R. P. ; Gener, M. ; Rousseau, Roger ; Canadell, E. ; Kushch, L. A. ; Yagubskii, E. B. ; Drozdova, O. O. ; Yakushi, K. / A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]. In: Journal of Materials Chemistry. 2000 ; Vol. 10, No. 9. pp. 2017-2023.
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abstract = "(BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) {\AA}, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) {\AA}3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.",
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T1 - A new stable organic metal based on the BEDO-TTF donor and the doubly charged nitroprusside anion, (BEDO-TTF)4[Fe(CN)5NO]

AU - Zorina, L. V.

AU - Khasanov, S. S.

AU - Shibaeva, R. P.

AU - Gener, M.

AU - Rousseau, Roger

AU - Canadell, E.

AU - Kushch, L. A.

AU - Yagubskii, E. B.

AU - Drozdova, O. O.

AU - Yakushi, K.

PY - 2000

Y1 - 2000

N2 - (BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) Å, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) Å3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.

AB - (BEDO-TTF)4[Fe(CN)5NO] was synthesized by electrocrystallization using the nitroprussides M2[Fe(CN)5NO]·2H2O (M = K, Rb) as supporting electrolytes and TCE (1,1,2-trichloroethane) and DCE (1,2-dichloroethane) as solvents. The crystal structure of this new salt (a = 4.0251(3), b = 15.266(2), c = 19.259(2) Å, α = 97.02(1), β = 93.23(1), γ = 96.04(1)°, V = 1165.1(2) Å3, Z = 3/4, space group P1) is characterized by the presence of β'-type radical cation layers and anion layers containing disordered nitroprusside anions. The stoichiometry was confirmed by a micro-Raman spectroscopic study and the band structure and Fermi surface of this new salt were studied by means of the extended Huckel tight binding method. (BEDO-TTF)4[Fe(CN)5NO] is a two dimensional metal stable down to liquid helium temperatures.

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