A new type of coordination polymer: Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4

Brenda R. Cabrera; R. U J I Wang; Jing Li; T. A N Yuen

A new type of coordination polymer: Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4

Brenda R. Cabrera, R. U J I Wang, Jing Li, T. A N Yuen

Rutgers University

Research output: Chapter in Book/Report/Conference proceeding › Chapter

4 Citations (Scopus)

Abstract

Growth of [(C₁₀H₈N₂)₂CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of ¹[(Cu₃Br₄)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.

Original language	English
Title of host publication	Materials Research Society Symposium - Proceedings
Pages	493-498
Number of pages	6
Volume	547
Publication status	Published - 1999

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials

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title = "A new type of coordination polymer: Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4",

abstract = "Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.",

author = "Cabrera, {Brenda R.} and Wang, {R. U J I} and Jing Li and Yuen, {T. A N}",

year = "1999",

language = "English",

volume = "547",

pages = "493--498",

booktitle = "Materials Research Society Symposium - Proceedings",

}

TY - CHAP

T1 - A new type of coordination polymer

T2 - Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4

AU - Cabrera, Brenda R.

AU - Wang, R. U J I

AU - Li, Jing

AU - Yuen, T. A N

PY - 1999

Y1 - 1999

N2 - Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.

AB - Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.

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VL - 547

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EP - 498

BT - Materials Research Society Symposium - Proceedings

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