Abstract
Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.
| Original language | English |
|---|---|
| Title of host publication | Materials Research Society Symposium - Proceedings |
| Pages | 493-498 |
| Number of pages | 6 |
| Volume | 547 |
| Publication status | Published - 1999 |
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ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
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A new type of coordination polymer : Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4. / Cabrera, Brenda R.; Wang, R. U J I; Li, Jing; Yuen, T. A N.
Materials Research Society Symposium - Proceedings. Vol. 547 1999. p. 493-498.Research output: Chapter in Book/Report/Conference proceeding › Chapter
}
TY - CHAP
T1 - A new type of coordination polymer
T2 - Hydrothermal synthesis, crystal structure, and magnetic properties of [(C10H8N2)2CuBr]Cu 3Br4
AU - Cabrera, Brenda R.
AU - Wang, R. U J I
AU - Li, Jing
AU - Yuen, T. A N
PY - 1999
Y1 - 1999
N2 - Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.
AB - Growth of [(C10H8N2)2CuBr]Cu3Br4(I) crystals was achieved using the hydrothermal synthesis. Single crystal X-ray diffraction analysis shows that this compound crystallizes in monoclinic system, space group P2j/c (no. 14) with four formula units in the unit cell The cell dimensions are the following: a = 16.769(2) A, b = 23.873(6) A, c = 6.523(2) A, b= 98.37(3)°, V = 2584(1) A3. The title compound represents a new structure type. It consists of one-dimensional ribbons of 1[(Cu3Br4)] extending along the c-axis and discrete [(CioH8Nj)2CuBr]+ complexes. The magnetic susceptibility study indicates a paramagnetic behavior due to the Cu(II) in the complex cations. The effective paramagnetic moment was calculated to be 2.20 fa from fitting the x(T) data.
UR - http://www.scopus.com/inward/record.url?scp=0032591289&partnerID=8YFLogxK
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M3 - Chapter
VL - 547
SP - 493
EP - 498
BT - Materials Research Society Symposium - Proceedings
ER -