A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation

Peng Hu, Eran Fogler, Yael Diskin-Posner, Mark A. Iron, David Milstein

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

Hydrogen is an efficient green fuel, but its low energy density when stored under high pressure or cryogenically, and safety issues, presents significant disadvantages; hence finding efficient and safe hydrogen carriers is a major challenge. Of special interest are liquid organic hydrogen carriers (LOHCs), which can be readily loaded and unloaded with considerable amounts of hydrogen. However, disadvantages include high hydrogen pressure requirements, high reaction temperatures for both hydrogenation and dehydrogenation steps, which require different catalysts, and high LOHC cost. Here we present a readily reversible LOHC system based on catalytic peptide formation and hydrogenation, using an inexpensive, safe and abundant organic compound with high potential capacity to store and release hydrogen, applying the same catalyst for loading and unloading hydrogen under relatively mild conditions. Mechanistic insight of the catalytic reaction is provided. We believe that these findings may lead to the development of an inexpensive, safe and clean liquid hydrogen carrier system.

Original languageEnglish
Article number7859
JournalNature Communications
Volume6
DOIs
Publication statusPublished - Apr 17 2015

Fingerprint

organic liquids
Hydrogenation
wireless communication
hydrogenation
peptides
Hydrogen
Peptides
Liquids
hydrogen
catalysts
liquid hydrogen
Pressure
unloading
Catalysts
dehydrogenation
organic compounds
Dehydrogenation
Unloading
Organic compounds
safety

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)
  • Chemistry(all)
  • Physics and Astronomy(all)

Cite this

A novel liquid organic hydrogen carrier system based on catalytic peptide formation and hydrogenation. / Hu, Peng; Fogler, Eran; Diskin-Posner, Yael; Iron, Mark A.; Milstein, David.

In: Nature Communications, Vol. 6, 7859, 17.04.2015.

Research output: Contribution to journalArticle

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