Abstract
(Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 3603-3606 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - Apr 28 2008 |
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Keywords
- C-F activation
- Electron transfer
- P ligands
- Platinum
- Reduction
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
A pincer-type anionic platinum(0) complex. / Schwartsburd, Leonid; Cohen, Revital; Konstantinovski, Leonid; Milstein, David.
In: Angewandte Chemie - International Edition, Vol. 47, No. 19, 28.04.2008, p. 3603-3606.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - A pincer-type anionic platinum(0) complex
AU - Schwartsburd, Leonid
AU - Cohen, Revital
AU - Konstantinovski, Leonid
AU - Milstein, David
PY - 2008/4/28
Y1 - 2008/4/28
N2 - (Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
AB - (Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
KW - C-F activation
KW - Electron transfer
KW - P ligands
KW - Platinum
KW - Reduction
UR - http://www.scopus.com/inward/record.url?scp=53549117738&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=53549117738&partnerID=8YFLogxK
U2 - 10.1002/anie.200705927
DO - 10.1002/anie.200705927
M3 - Article
VL - 47
SP - 3603
EP - 3606
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 19
ER -