TY - JOUR
T1 - A pincer-type anionic platinum(0) complex
AU - Schwartsburd, Leonid
AU - Cohen, Revital
AU - Konstantinovski, Leonid
AU - Milstein, David
PY - 2008/4/28
Y1 - 2008/4/28
N2 - (Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
AB - (Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
KW - C-F activation
KW - Electron transfer
KW - P ligands
KW - Platinum
KW - Reduction
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U2 - 10.1002/anie.200705927
DO - 10.1002/anie.200705927
M3 - Article
C2 - 18383469
AN - SCOPUS:53549117738
VL - 47
SP - 3603
EP - 3606
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 19
ER -