A pincer-type anionic platinum(0) complex

Leonid Schwartsburd, Revital Cohen, Leonid Konstantinovski, David Milstein

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

(Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).

Original languageEnglish
Pages (from-to)3603-3606
Number of pages4
JournalAngewandte Chemie - International Edition
Volume47
Issue number19
DOIs
Publication statusPublished - Apr 28 2008

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Protonation
Platinum
Hydrides
Anions
Negative ions
Chemical activation
Electrons
Water

Keywords

  • C-F activation
  • Electron transfer
  • P ligands
  • Platinum
  • Reduction

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

A pincer-type anionic platinum(0) complex. / Schwartsburd, Leonid; Cohen, Revital; Konstantinovski, Leonid; Milstein, David.

In: Angewandte Chemie - International Edition, Vol. 47, No. 19, 28.04.2008, p. 3603-3606.

Research output: Contribution to journalArticle

Schwartsburd, L, Cohen, R, Konstantinovski, L & Milstein, D 2008, 'A pincer-type anionic platinum(0) complex', Angewandte Chemie - International Edition, vol. 47, no. 19, pp. 3603-3606. https://doi.org/10.1002/anie.200705927
Schwartsburd, Leonid ; Cohen, Revital ; Konstantinovski, Leonid ; Milstein, David. / A pincer-type anionic platinum(0) complex. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 19. pp. 3603-3606.
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