Abstract
(Chemical Presented) Holding a Pt0 anion in a pincer: Reduction of the pincer-type PtII complex 1 results in the formation of the thermally stable anionic Pt0 complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt II. Protonation of 2 with water gives a PtII hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 3603-3606 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 47 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - Apr 28 2008 |
Keywords
- C-F activation
- Electron transfer
- P ligands
- Platinum
- Reduction
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Schwartsburd, L., Cohen, R., Konstantinovski, L., & Milstein, D. (2008). A pincer-type anionic platinum(0) complex. Angewandte Chemie - International Edition, 47(19), 3603-3606. https://doi.org/10.1002/anie.200705927