A pincer-type anionic platinum(0) complex

Leonid Schwartsburd; Revital Cohen; Leonid Konstantinovski; David Milstein

doi:10.1002/anie.200705927

A pincer-type anionic platinum(0) complex

Leonid Schwartsburd, Revital Cohen, Leonid Konstantinovski, David Milstein

Weizmann Institute of Science, Israel

Research output: Contribution to journal › Article

27 Citations (Scopus)

Abstract

(Chemical Presented) Holding a Pt⁰ anion in a pincer: Reduction of the pincer-type Pt^II complex 1 results in the formation of the thermally stable anionic Pt⁰ complex 2. This complex adopts a T-shaped structure and exhibits diverse reactivity, including efficient electron-transfer processes in which 2 is reoxidized quantitatively to Pt ^II. Protonation of 2 with water gives a Pt^II hydride complex, and C-F activation under mild conditions leads to 3 (see scheme).

Original language	English
Pages (from-to)	3603-3606
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	19
DOIs	https://doi.org/10.1002/anie.200705927
Publication status	Published - Apr 28 2008

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Keywords

C-F activation
Electron transfer
P ligands
Platinum
Reduction

ASJC Scopus subject areas

Catalysis
Chemistry(all)

Cite this

Schwartsburd, L., Cohen, R., Konstantinovski, L., & Milstein, D. (2008). A pincer-type anionic platinum(0) complex. Angewandte Chemie - International Edition, 47(19), 3603-3606. https://doi.org/10.1002/anie.200705927

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Access to Document

10.1002/anie.200705927