A polar and chiral indium telluride featuring supertetrahedral T2 clusters and nonlinear optical second harmonic generation

Qichun Zhang, In Chung, Joon I. Jang, John B. Ketterson, Mercouri G. Kanatzidis

Research output: Contribution to journalArticle

82 Citations (Scopus)

Abstract

The intermetallic Zintl phase of nominal composition was reported to react with the Te to produce a layered chiral compound with truncated adamantane clusters. The crystal structure of the Te compound was determined from single-crystal X-ray diffraction data collected at 100K on a STOE II X-ray diffractometer. The arrangement of In-Te network if found to create windows of size 0.81 nm within the layers defined by 18-membered rings formed by nine tetrahedral indium sites. The total charge of each window is found to be -3 and is balanced by octahedral, which occupy the middle of each window. The distance between adjacent layers of Te compound is approximately 0.5 Å, which is filled by one-half of each metal complex, the terminal en molecules, and disordered free en molecules. The solid-state UV-vis absorption of a single crystal of Te compound reveal an absorption edge at approximately 2.2 eV, consistent with its orange color.

Original languageEnglish
Pages (from-to)12-14
Number of pages3
JournalChemistry of Materials
Volume21
Issue number1
DOIs
Publication statusPublished - Jan 13 2009

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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