A rare terminal dinitrogen complex of chromium

Michael T. Mock; Shentan Chen; Roger Rousseau; Molly J. O'Hagan; William G. Dougherty; W. Scott Kassel; Daniel L. Dubois; R. Morris Bullock

doi:10.1039/c1cc15430c

A rare terminal dinitrogen complex of chromium

Michael T. Mock, Shentan Chen, Roger Rousseau, Molly J. O'Hagan, William G. Dougherty, W. Scott Kassel, Daniel L. Dubois, R. Morris Bullock

Pacific Northwest National Laboratory

Research output: Contribution to journal › Article

31 Citations (Scopus)

Abstract

Cis and trans-Cr-N₂ complexes supported by the diphosphine ligand P^Ph₂N^Bn₂ have been prepared. Positioned pendant amines in the second coordination sphere influence the thermodynamically preferred geometric isomer. Electronic structure calculations indicate negligible Cr-N₂ back-bonding; rather, electronic polarization of N₂ ligand is thought to stabilize Cr-N₂ binding.

Original language	English
Pages (from-to)	12212-12214
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	44
DOIs	https://doi.org/10.1039/c1cc15430c
Publication status	Published - Nov 28 2011

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c1cc15430c

Fingerprint Dive into the research topics of 'A rare terminal dinitrogen complex of chromium'. Together they form a unique fingerprint.

Cite this

Mock, M. T., Chen, S., Rousseau, R., O'Hagan, M. J., Dougherty, W. G., Kassel, W. S., Dubois, D. L., & Bullock, R. M. (2011). A rare terminal dinitrogen complex of chromium. Chemical Communications, 47(44), 12212-12214. https://doi.org/10.1039/c1cc15430c

@article{8ce8d94d984d4212b32cd7a7a4461406,

title = "A rare terminal dinitrogen complex of chromium",

abstract = "Cis and trans-Cr-N2 complexes supported by the diphosphine ligand PPh2NBn2 have been prepared. Positioned pendant amines in the second coordination sphere influence the thermodynamically preferred geometric isomer. Electronic structure calculations indicate negligible Cr-N2 back-bonding; rather, electronic polarization of N2 ligand is thought to stabilize Cr-N2 binding.",

author = "Mock, {Michael T.} and Shentan Chen and Roger Rousseau and O'Hagan, {Molly J.} and Dougherty, {William G.} and Kassel, {W. Scott} and Dubois, {Daniel L.} and Bullock, {R. Morris}",

year = "2011",

month = nov,

day = "28",

doi = "10.1039/c1cc15430c",

language = "English",

volume = "47",

pages = "12212--12214",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "44",

}

TY - JOUR

T1 - A rare terminal dinitrogen complex of chromium

AU - Mock, Michael T.

AU - Chen, Shentan

AU - Rousseau, Roger

AU - O'Hagan, Molly J.

AU - Dougherty, William G.

AU - Kassel, W. Scott

AU - Dubois, Daniel L.

AU - Bullock, R. Morris

PY - 2011/11/28

Y1 - 2011/11/28

N2 - Cis and trans-Cr-N2 complexes supported by the diphosphine ligand PPh2NBn2 have been prepared. Positioned pendant amines in the second coordination sphere influence the thermodynamically preferred geometric isomer. Electronic structure calculations indicate negligible Cr-N2 back-bonding; rather, electronic polarization of N2 ligand is thought to stabilize Cr-N2 binding.

AB - Cis and trans-Cr-N2 complexes supported by the diphosphine ligand PPh2NBn2 have been prepared. Positioned pendant amines in the second coordination sphere influence the thermodynamically preferred geometric isomer. Electronic structure calculations indicate negligible Cr-N2 back-bonding; rather, electronic polarization of N2 ligand is thought to stabilize Cr-N2 binding.

UR - http://www.scopus.com/inward/record.url?scp=80155133633&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=80155133633&partnerID=8YFLogxK

U2 - 10.1039/c1cc15430c

DO - 10.1039/c1cc15430c

M3 - Article

C2 - 21993453

AN - SCOPUS:80155133633

VL - 47

SP - 12212

EP - 12214

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 44

ER -