A rate constant expression for charge transfer through fluctuating bridges

Alessandro Troisi, Abraham Nitzan, Mark A Ratner

Research output: Contribution to journalArticle

108 Citations (Scopus)

Abstract

A rate constant expression was presented for charge transfer reactions mediated by flexible bridges. It was found that the leading term corresponds to the static limit which was obtained from the Condon approximation. The corrections due to finite time fluctuations were also evaluated.

Original languageEnglish
Pages (from-to)5782-5788
Number of pages7
JournalJournal of Chemical Physics
Volume119
Issue number12
DOIs
Publication statusPublished - Sep 22 2003

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Charge transfer
Rate constants
charge transfer
approximation

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

A rate constant expression for charge transfer through fluctuating bridges. / Troisi, Alessandro; Nitzan, Abraham; Ratner, Mark A.

In: Journal of Chemical Physics, Vol. 119, No. 12, 22.09.2003, p. 5782-5788.

Research output: Contribution to journalArticle

Troisi, Alessandro ; Nitzan, Abraham ; Ratner, Mark A. / A rate constant expression for charge transfer through fluctuating bridges. In: Journal of Chemical Physics. 2003 ; Vol. 119, No. 12. pp. 5782-5788.
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