TY - JOUR
T1 - A Robust Squarate-Based Metal-Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton
AU - Li, Liangying
AU - Guo, Lidong
AU - Zhang, Zhiguo
AU - Yang, Qiwei
AU - Yang, Yiwen
AU - Bao, Zongbi
AU - Ren, Qilong
AU - Li, Jing
PY - 2019/6/12
Y1 - 2019/6/12
N2 - The efficient separation of xenon (Xe) and krypton (Kr) is one of the industrially important processes. While adsorptive separation of these two species is considered to be an energy efficient process, developing highly selective adsorbent remains challenging. Herein, a rigid squarate-based metal-organic framework (MOF), having a perfect pore size (4.1 Å × 4.3 Å) comparable with the kinetic diameter of Xe (4.047 Å) as well as pore surface decorated with very polar hydroxyl groups, is able to effectively discriminate Xe atoms, affording a record-high Xe/Kr selectivity. An exceptionally high Xe uptake capacity of 58.4 cm3/cm3 and selectivity of 60.6 at low pressure (0.2 bar) are achieved at ambient temperature. The MOF exhibits the highest Xe Henry coefficient (192.1 mmol/g/bar) and Xe/Kr Henry selectivity (54.1) among all state-of-the-art adsorbents reported so far. Direct breakthrough experiments further confirm the excellent separation performance. The density functional theory calculations reveal that the strong interaction between Xe and the framework is a result of the synergy between optimal pore size and polar porosity.
AB - The efficient separation of xenon (Xe) and krypton (Kr) is one of the industrially important processes. While adsorptive separation of these two species is considered to be an energy efficient process, developing highly selective adsorbent remains challenging. Herein, a rigid squarate-based metal-organic framework (MOF), having a perfect pore size (4.1 Å × 4.3 Å) comparable with the kinetic diameter of Xe (4.047 Å) as well as pore surface decorated with very polar hydroxyl groups, is able to effectively discriminate Xe atoms, affording a record-high Xe/Kr selectivity. An exceptionally high Xe uptake capacity of 58.4 cm3/cm3 and selectivity of 60.6 at low pressure (0.2 bar) are achieved at ambient temperature. The MOF exhibits the highest Xe Henry coefficient (192.1 mmol/g/bar) and Xe/Kr Henry selectivity (54.1) among all state-of-the-art adsorbents reported so far. Direct breakthrough experiments further confirm the excellent separation performance. The density functional theory calculations reveal that the strong interaction between Xe and the framework is a result of the synergy between optimal pore size and polar porosity.
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U2 - 10.1021/jacs.9b03422
DO - 10.1021/jacs.9b03422
M3 - Article
C2 - 31091084
AN - SCOPUS:85066444214
VL - 141
SP - 9358
EP - 9364
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 23
ER -