A Robust Squarate-Based Metal-Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton

Liangying Li, Lidong Guo, Zhiguo Zhang, Qiwei Yang, Yiwen Yang, Zongbi Bao, Qilong Ren, Jing Li

Research output: Contribution to journalArticle

Abstract

The efficient separation of xenon (Xe) and krypton (Kr) is one of the industrially important processes. While adsorptive separation of these two species is considered to be an energy efficient process, developing highly selective adsorbent remains challenging. Herein, a rigid squarate-based metal-organic framework (MOF), having a perfect pore size (4.1 Å × 4.3 Å) comparable with the kinetic diameter of Xe (4.047 Å) as well as pore surface decorated with very polar hydroxyl groups, is able to effectively discriminate Xe atoms, affording a record-high Xe/Kr selectivity. An exceptionally high Xe uptake capacity of 58.4 cm3/cm3 and selectivity of 60.6 at low pressure (0.2 bar) are achieved at ambient temperature. The MOF exhibits the highest Xe Henry coefficient (192.1 mmol/g/bar) and Xe/Kr Henry selectivity (54.1) among all state-of-the-art adsorbents reported so far. Direct breakthrough experiments further confirm the excellent separation performance. The density functional theory calculations reveal that the strong interaction between Xe and the framework is a result of the synergy between optimal pore size and polar porosity.

Original languageEnglish
Pages (from-to)9358-9364
Number of pages7
JournalJournal of the American Chemical Society
Volume141
Issue number23
DOIs
Publication statusPublished - Jun 12 2019

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Krypton
Xenon
Metals
Adsorbents
Pore size
Porosity
Hydroxyl Radical
Density functional theory
Pressure
Atoms
Kinetics
Temperature

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

A Robust Squarate-Based Metal-Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton. / Li, Liangying; Guo, Lidong; Zhang, Zhiguo; Yang, Qiwei; Yang, Yiwen; Bao, Zongbi; Ren, Qilong; Li, Jing.

In: Journal of the American Chemical Society, Vol. 141, No. 23, 12.06.2019, p. 9358-9364.

Research output: Contribution to journalArticle

Li, Liangying ; Guo, Lidong ; Zhang, Zhiguo ; Yang, Qiwei ; Yang, Yiwen ; Bao, Zongbi ; Ren, Qilong ; Li, Jing. / A Robust Squarate-Based Metal-Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 23. pp. 9358-9364.
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