A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

Pei Yao Du; William P. Lustig; Simon J. Teat; Wen Gu; Xin Liu; Jing Li

doi:10.1039/c8cc03496f

A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

Pei Yao Du, William P. Lustig, Simon J. Teat, Wen Gu, Xin Liu, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr₆(sdba)₄(μ₃-O)₄(μ₃-OH)₄(HCOO)₂(OH)₂(H₂O)₂ (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.

Original language	English
Pages (from-to)	8088-8091
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	58
DOIs	https://doi.org/10.1039/c8cc03496f
Publication status	Published - 2018

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds. / Du, Pei Yao; Lustig, William P.; Teat, Simon J.; Gu, Wen; Liu, Xin; Li, Jing.

In: Chemical Communications, Vol. 54, No. 58, 2018, p. 8088-8091.

Research output: Contribution to journal › Article › peer-review

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title = "A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds",

abstract = "We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr6(sdba)4(μ3-O)4(μ3-OH)4(HCOO)2(OH)2(H2O)2 (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.",

author = "Du, {Pei Yao} and Lustig, {William P.} and Teat, {Simon J.} and Wen Gu and Xin Liu and Jing Li",

note = "Funding Information: We acknowledge the financial support of the Department of Energy, Basic Energy Sciences, and Division of Materials Sciences and Engineering through Grant No. DE-FG02-08ER-46491. The Advanced Light Source is supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Pei-Yao Du, Xin Liu and Wen Gu thank the National Natural Science Foundation of China (Grant No. 21371103) and 111 Project (B12015) for their support. Pei-Yao Du gratefully acknowledges the financial support of the China Scholarship Council (CSC, 201606200043) to support her study at Rutgers University.",

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AU - Gu, Wen

AU - Liu, Xin

AU - Li, Jing

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N2 - We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr6(sdba)4(μ3-O)4(μ3-OH)4(HCOO)2(OH)2(H2O)2 (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.

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