A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

Pei Yao Du; William P. Lustig; Simon J. Teat; Wen Gu; Xin Liu; Jing Li

doi:10.1039/c8cc03496f

A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds

Pei Yao Du, William P. Lustig, Simon J. Teat, Wen Gu, Xin Liu, Jing Li

Rutgers University

Research output: Contribution to journal › Article

15 Citations (Scopus)

Abstract

We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr₆(sdba)₄(μ₃-O)₄(μ₃-OH)₄(HCOO)₂(OH)₂(H₂O)₂ (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.

Original language	English
Pages (from-to)	8088-8091
Number of pages	4
Journal	Chemical Communications
Volume	54
Issue number	58
DOIs	https://doi.org/10.1039/c8cc03496f
Publication status	Published - Jan 1 2018

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ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Cite this

Du, P. Y., Lustig, W. P., Teat, S. J., Gu, W., Liu, X., & Li, J. (2018). A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds. Chemical Communications, 54(58), 8088-8091. https://doi.org/10.1039/c8cc03496f

A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds. / Du, Pei Yao; Lustig, William P.; Teat, Simon J.; Gu, Wen; Liu, Xin; Li, Jing.

In: Chemical Communications, Vol. 54, No. 58, 01.01.2018, p. 8088-8091.

Research output: Contribution to journal › Article

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10.1039/c8cc03496f