Abstract
We report herein a new two-dimensional zirconium-based luminescent coordination polymer Zr6(sdba)4(μ3-O)4(μ3-OH)4(HCOO)2(OH)2(H2O)2 (1) [sdba = 4,4′-sulfonyldibenzoate] exhibiting selective fluorescence responses towards a variety of volatile organic compounds upon exposure in the vapor phase. Having a unique two-dimensional signal response towards aromatic molecules, including but not limited to nitroaromatic explosives, it is capable of identifying a diverse set of analytes. In addition, compound 1 shows its remarkably high sensitivity toward acetone vapors.
| Original language | English |
|---|---|
| Pages (from-to) | 8088-8091 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 54 |
| Issue number | 58 |
| DOIs | |
| Publication status | Published - Jan 1 2018 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry
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Cite this
Du, P. Y., Lustig, W. P., Teat, S. J., Gu, W., Liu, X., & Li, J. (2018). A robust two-dimensional zirconium-based luminescent coordination polymer built on a V-shaped dicarboxylate ligand for vapor phase sensing of volatile organic compounds. Chemical Communications, 54(58), 8088-8091. https://doi.org/10.1039/c8cc03496f