Abstract
The self-consistent-field (SCF) approximation for coupled-vibron systems in the semiclassical limit yields Hartree-type equations, in which only the eigenenergies and turning points are self-consistently evaluated. Calculations yield vibrational energies in excellent agreement with quantum SCF and exact quantum results. Applications and extensions are briefly discussed.
Original language | English |
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Pages (from-to) | 195-198 |
Number of pages | 4 |
Journal | Chemical Physics Letters |
Volume | 68 |
Issue number | 1 |
DOIs | |
Publication status | Published - Dec 1 1979 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces