A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4

Jeong Yong Lee; Long Pan; Xiaoying Huang; Thomas J. Emge; Jing Li

doi:10.1002/adfm.201001790

A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H₂ and CH₄

Jeong Yong Lee, Long Pan, Xiaoying Huang, Thomas J. Emge, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)_0.5 and Ni(NDC)(TED)_0.5 adsorb 242 cm³ g^-1 and 173 cm³ g^-1 of CH ₄, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.

Original language	English
Pages (from-to)	993-998
Number of pages	6
Journal	Advanced Functional Materials
Volume	21
Issue number	5
DOIs	https://doi.org/10.1002/adfm.201001790
Publication status	Published - Mar 8 2011

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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AB - Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.

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