TY - JOUR
T1 - A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4
AU - Lee, Jeong Yong
AU - Pan, Long
AU - Huang, Xiaoying
AU - Emge, Thomas J.
AU - Li, Jing
PY - 2011/3/8
Y1 - 2011/3/8
N2 - Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
AB - Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
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U2 - 10.1002/adfm.201001790
DO - 10.1002/adfm.201001790
M3 - Article
AN - SCOPUS:79952137147
VL - 21
SP - 993
EP - 998
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
IS - 5
ER -