Abstract
Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 993-998 |
| Number of pages | 6 |
| Journal | Advanced Functional Materials |
| Volume | 21 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Mar 8 2011 |
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ASJC Scopus subject areas
- Biomaterials
- Electrochemistry
- Condensed Matter Physics
- Electronic, Optical and Magnetic Materials
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A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4 . / Lee, Jeong Yong; Pan, Long; Huang, Xiaoying; Emge, Thomas J.; Li, Jing.
In: Advanced Functional Materials, Vol. 21, No. 5, 08.03.2011, p. 993-998.Research output: Contribution to journal › Article
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TY - JOUR
T1 - A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4
AU - Lee, Jeong Yong
AU - Pan, Long
AU - Huang, Xiaoying
AU - Emge, Thomas J.
AU - Li, Jing
PY - 2011/3/8
Y1 - 2011/3/8
N2 - Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
AB - Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
UR - http://www.scopus.com/inward/record.url?scp=79952137147&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79952137147&partnerID=8YFLogxK
U2 - 10.1002/adfm.201001790
DO - 10.1002/adfm.201001790
M3 - Article
AN - SCOPUS:79952137147
VL - 21
SP - 993
EP - 998
JO - Advanced Functional Materials
JF - Advanced Functional Materials
SN - 1616-301X
IS - 5
ER -