A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4

Jeong Yong Lee, Long Pan, Xiaoying Huang, Thomas J. Emge, Jing Li

Research output: Contribution to journalArticle

60 Citations (Scopus)

Abstract

Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.

Original languageEnglish
Pages (from-to)993-998
Number of pages6
JournalAdvanced Functional Materials
Volume21
Issue number5
DOIs
Publication statusPublished - Mar 8 2011

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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