Abstract
Highly porous metal organic framework materials having closely related structures and systematically tunable porosity demonstrate a high capacity for methane and hydrogen adsorption. At room temperature and ∼40 bars, the compounds Zn(BDC)(TED)0.5 and Ni(NDC)(TED)0.5 adsorb 242 cm3 g-1 and 173 cm3 g-1 of CH 4, respectively. At 77 K, they take up 4.1 and 5.5 wt% of hydrogen at 40 and 65 bars, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 993-998 |
| Number of pages | 6 |
| Journal | Advanced Functional Materials |
| Volume | 21 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Mar 8 2011 |
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
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Lee, J. Y., Pan, L., Huang, X., Emge, T. J., & Li, J. (2011). A systematic approach to building highly porous, noninterpenetrating metal-organic frameworks with a large capacity for adsorbing H2 and CH4. Advanced Functional Materials, 21(5), 993-998. https://doi.org/10.1002/adfm.201001790