A systematic study of fluorescence-based detection of nitroexplosives and other aromatics in the vapor phase by microporous metal-organic frameworks

Sanhita Pramanik, Zhichao Hu, Xiao Zhang, Chong Zheng, Sean Kelly, Jing Li

Research output: Contribution to journalArticle

137 Citations (Scopus)

Abstract

A systematic study is conducted on four microporous metal-organic framework compounds built on similar ligands but different structures, namely [Zn 3(bpdc)3(bpy)]×4 DMF×H2O (1), [Zn3(bpdc)3(2,2′dmbpy)]×4 DMF× H 2O (2), [Zn2(bpdc)2(bpe)]×2 DMF (3), and [Zn(bpdc)(bpe)]×DMF (4) (bpdc=4,4′-biphenyldicarboxylate; bpy=4,4′-bipyridine; 2,2′dmbpy=2,2′-dimethyl-4, 4′bipyridine; bpe=1,2-bis(4-pyridyl)ethane; DMF=N,N′- dimethylformamide) to investigate their photoluminescence properties and sensing/detection behavior upon exposure to vapors of various aromatic molecules (analytes) including nitroaromatic explosives. The results show that all four compounds are capable of detecting these molecules in the vapor phase through fluorescence quenching or enhancement. Both electrochemical measurements and theoretical calculations are performed to analyze the analyte-MOF interactions, to explain the difference in signal response by different analytes, and to understand the mechanism of fluorescence quenching or enhancement observed in these systems. Interestingly, compound 3 also shows an emission frequency shift when exposed to benzene (BZ), chlorobenzene (ClBZ), and toluene (TO), which provides an additional variable for the identification of different analytes in the same category.

Original languageEnglish
Pages (from-to)15964-15971
Number of pages8
JournalChemistry - A European Journal
Volume19
Issue number47
DOIs
Publication statusPublished - Nov 18 2013

Fingerprint

Quenching
Metals
Fluorescence
Vapors
Dimethylformamide
Molecules
Ethane
Toluene
Benzene
Organic compounds
Photoluminescence
Ligands
3'-dimethylaminoflavone
chlorobenzene

Keywords

  • aromatics
  • detection
  • explosives
  • luminescence
  • metal-organic framework
  • sensing

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

A systematic study of fluorescence-based detection of nitroexplosives and other aromatics in the vapor phase by microporous metal-organic frameworks. / Pramanik, Sanhita; Hu, Zhichao; Zhang, Xiao; Zheng, Chong; Kelly, Sean; Li, Jing.

In: Chemistry - A European Journal, Vol. 19, No. 47, 18.11.2013, p. 15964-15971.

Research output: Contribution to journalArticle

Pramanik, Sanhita ; Hu, Zhichao ; Zhang, Xiao ; Zheng, Chong ; Kelly, Sean ; Li, Jing. / A systematic study of fluorescence-based detection of nitroexplosives and other aromatics in the vapor phase by microporous metal-organic frameworks. In: Chemistry - A European Journal. 2013 ; Vol. 19, No. 47. pp. 15964-15971.
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