A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains

Jin Tang Li, Jun Tao, Rong Bin Huang, Lan Sun Zheng, Tan Yuen, C. L. Lin, Princy Varughese, Jing Li

Research output: Contribution to journalArticle

27 Citations (Scopus)

Abstract

A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

Original languageEnglish
Pages (from-to)4448-4450
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number13
DOIs
Publication statusPublished - Jun 27 2005

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Sodium Azide
Manganese
coordination polymers
hydroxides
manganese
Polymers
Crystal structure
Single crystals
moments
X ray diffraction
acids
crystal structure
Acids
Water
single crystals
diffraction
water
x rays
interactions
manganese chloride

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains. / Li, Jin Tang; Tao, Jun; Huang, Rong Bin; Zheng, Lan Sun; Yuen, Tan; Lin, C. L.; Varughese, Princy; Li, Jing.

In: Inorganic Chemistry, Vol. 44, No. 13, 27.06.2005, p. 4448-4450.

Research output: Contribution to journalArticle

Li, Jin Tang ; Tao, Jun ; Huang, Rong Bin ; Zheng, Lan Sun ; Yuen, Tan ; Lin, C. L. ; Varughese, Princy ; Li, Jing. / A three-dimensional coordination polymer featuring effective ferrimagnetic hydroxide-bridged manganese(II) chains. In: Inorganic Chemistry. 2005 ; Vol. 44, No. 13. pp. 4448-4450.
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AB - A three-dimensional coordination polymer, [Mn3(OH) 2Na2(3-cnba)6]n (1) (3-Hcnba = 3-cyanobenzoic acid), has been synthesized by the reaction of MnCl2, NaN3, and 3-Hcnba in water. Its crystal structure was determined by single-crystal X-ray diffraction. Magnetic studies show that the complex behaves as a three-dimensional metamagnet built from effective ferrimagnetic Mn(II) chains in which spin moments are linked by interactions in an AF-F-AF (F = ferromagnetic and AF = antiferromagnetic) sequence in the triangular magnetic repeating unit.

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