A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca; Steven J. Konezny; James D. Blakemore; Dominic M. Colosi; Shubhro Saha; Gary W. Brudvig; Victor S. Batista; Robert H. Crabtree

doi:10.1039/c2nj20912h

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W. Brudvig, Victor S. Batista, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article › peer-review

70 Citations (Scopus)

Abstract

A Ni^II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Original language	English
Pages (from-to)	1149-1152
Number of pages	4
Journal	New Journal of Chemistry
Volume	36
Issue number	5
DOIs	https://doi.org/10.1039/c2nj20912h
Publication status	Published - May 2012

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Materials Chemistry

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title = "A tridentate Ni pincer for aqueous electrocatalytic hydrogen production",

abstract = "A NiII complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.",

author = "Luca, {Oana R.} and Konezny, {Steven J.} and Blakemore, {James D.} and Colosi, {Dominic M.} and Shubhro Saha and Brudvig, {Gary W.} and Batista, {Victor S.} and Crabtree, {Robert H.}",

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AU - Luca, Oana R.

AU - Konezny, Steven J.

AU - Blakemore, James D.

AU - Colosi, Dominic M.

AU - Saha, Shubhro

AU - Brudvig, Gary W.

AU - Batista, Victor S.

AU - Crabtree, Robert H.

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JO - New Journal of Chemistry

JF - New Journal of Chemistry

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A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Abstract

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