A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W Brudvig, Victor S. Batista, Robert H. Crabtree

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

A Ni II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Original languageEnglish
Pages (from-to)1149-1152
Number of pages4
JournalNew Journal of Chemistry
Volume36
Issue number5
DOIs
Publication statusPublished - May 2012

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ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Cite this

Luca, O. R., Konezny, S. J., Blakemore, J. D., Colosi, D. M., Saha, S., Brudvig, G. W., ... Crabtree, R. H. (2012). A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal of Chemistry, 36(5), 1149-1152. https://doi.org/10.1039/c2nj20912h