A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca; Steven J. Konezny; James D. Blakemore; Dominic M. Colosi; Shubhro Saha; Gary W Brudvig; Victor S. Batista; Robert H. Crabtree

doi:10.1039/c2nj20912h

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W Brudvig, Victor S. Batista, Robert H. Crabtree

Yale University

Research output: Contribution to journal › Article

63 Citations (Scopus)

Abstract

A Ni ^II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Original language	English
Pages (from-to)	1149-1152
Number of pages	4
Journal	New Journal of Chemistry
Volume	36
Issue number	5
DOIs	https://doi.org/10.1039/c2nj20912h
Publication status	Published - May 2012

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ASJC Scopus subject areas

Chemistry(all)
Catalysis
Materials Chemistry

Cite this

Luca, O. R., Konezny, S. J., Blakemore, J. D., Colosi, D. M., Saha, S., Brudvig, G. W., ... Crabtree, R. H. (2012). A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal of Chemistry, 36(5), 1149-1152. https://doi.org/10.1039/c2nj20912h

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Access to Document

10.1039/c2nj20912h