A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W. Brudvig, Victor S. Batista, Robert H. Crabtree

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

A NiII complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Original languageEnglish
Pages (from-to)1149-1152
Number of pages4
JournalNew Journal of Chemistry
Volume36
Issue number5
DOIs
Publication statusPublished - May 2012

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Materials Chemistry

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    Luca, O. R., Konezny, S. J., Blakemore, J. D., Colosi, D. M., Saha, S., Brudvig, G. W., Batista, V. S., & Crabtree, R. H. (2012). A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal of Chemistry, 36(5), 1149-1152. https://doi.org/10.1039/c2nj20912h