A tridentate Ni pincer for aqueous electrocatalytic hydrogen production

Oana R. Luca, Steven J. Konezny, James D. Blakemore, Dominic M. Colosi, Shubhro Saha, Gary W Brudvig, Victor S. Batista, Robert H. Crabtree

Research output: Contribution to journalArticle

63 Citations (Scopus)

Abstract

A Ni II complex with a redox-active pincer ligand reduces protons at a low overpotential in aqueous acidic conditions. A combined experimental and computational study provides mechanistic insights into a putative catalytic cycle.

Original languageEnglish
Pages (from-to)1149-1152
Number of pages4
JournalNew Journal of Chemistry
Volume36
Issue number5
DOIs
Publication statusPublished - May 2012

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Hydrogen production
Protons
Ligands
Oxidation-Reduction

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Materials Chemistry

Cite this

Luca, O. R., Konezny, S. J., Blakemore, J. D., Colosi, D. M., Saha, S., Brudvig, G. W., ... Crabtree, R. H. (2012). A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. New Journal of Chemistry, 36(5), 1149-1152. https://doi.org/10.1039/c2nj20912h

A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. / Luca, Oana R.; Konezny, Steven J.; Blakemore, James D.; Colosi, Dominic M.; Saha, Shubhro; Brudvig, Gary W; Batista, Victor S.; Crabtree, Robert H.

In: New Journal of Chemistry, Vol. 36, No. 5, 05.2012, p. 1149-1152.

Research output: Contribution to journalArticle

Luca, OR, Konezny, SJ, Blakemore, JD, Colosi, DM, Saha, S, Brudvig, GW, Batista, VS & Crabtree, RH 2012, 'A tridentate Ni pincer for aqueous electrocatalytic hydrogen production', New Journal of Chemistry, vol. 36, no. 5, pp. 1149-1152. https://doi.org/10.1039/c2nj20912h
Luca, Oana R. ; Konezny, Steven J. ; Blakemore, James D. ; Colosi, Dominic M. ; Saha, Shubhro ; Brudvig, Gary W ; Batista, Victor S. ; Crabtree, Robert H. / A tridentate Ni pincer for aqueous electrocatalytic hydrogen production. In: New Journal of Chemistry. 2012 ; Vol. 36, No. 5. pp. 1149-1152.
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