A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration

Tendai Gadzikwa, Omar K. Farha, Karen L. Mulfort, Joseph T Hupp, Sonbinh T. Nguyen

Research output: Contribution to journalArticle

110 Citations (Scopus)

Abstract

A Zn-based, mixed-ligand (pillared paddlewheel), metal-organic framework (MOF) has been covalently and quantitatively decorated with free carboxylic acids to demonstrate the utility of covalent post-synthesis modification in the construction of otherwise inaccessible carboxy-functionalized MOFs.

Original languageEnglish
Pages (from-to)3720-3722
Number of pages3
JournalChemical Communications
Issue number25
DOIs
Publication statusPublished - 2009

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Carboxylic Acids
Carboxylic acids
Metals
Ligands

ASJC Scopus subject areas

  • Metals and Alloys
  • Materials Chemistry
  • Surfaces, Coatings and Films
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Catalysis
  • Chemistry(all)

Cite this

A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration. / Gadzikwa, Tendai; Farha, Omar K.; Mulfort, Karen L.; Hupp, Joseph T; Nguyen, Sonbinh T.

In: Chemical Communications, No. 25, 2009, p. 3720-3722.

Research output: Contribution to journalArticle

Gadzikwa, Tendai ; Farha, Omar K. ; Mulfort, Karen L. ; Hupp, Joseph T ; Nguyen, Sonbinh T. / A Zn-based, pillared paddlewheel MOF containing free carboxylic acids via covalent post-synthesis elaboration. In: Chemical Communications. 2009 ; No. 25. pp. 3720-3722.
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