Accumulative charge separation inspired by photosynthesis

Susanne Karlsson, Julien Boixel, Yann Pellegrin, Errol Blart, Hans Christian Becker, Fabrice Odobel, Leif Hammarström

Research output: Contribution to journalArticlepeer-review

78 Citations (Scopus)

Abstract

Molecular systems that follow the functional principles of photosynthesis have attracted increasing attention as a method for the direct production of solar fuels. This could give a major carbon-neutral energy contribution to our future society. An outstanding challenge in this research is to couple the light-induced charge separation (which generates a single electron-hole pair) to the multielectron processes of water oxidation and fuel generation. New design considerations are needed to allow for several cycles of photon absorption and charge separation of a single artificial photosystem. Here we demonstrate a molecular system with a regenerative photosensitizer that shows two successive events of light-induced charge separation, leading to high-yield accumulation of redox equivalents on single components without sacrificial agents.

Original languageEnglish
Pages (from-to)17977-17979
Number of pages3
JournalJournal of the American Chemical Society
Volume132
Issue number51
DOIs
Publication statusPublished - Dec 29 2010

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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