Acid-induced conversions in open-framework semiconductors

From [Cd 4Sn3Se13]6- to [Cd 15Sn12Se46]14-, a remarkable disassembly/reassembly process

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)

Original languageEnglish
Pages (from-to)1397-1401
Number of pages5
JournalAngewandte Chemie - International Edition
Volume45
Issue number9
DOIs
Publication statusPublished - Feb 20 2006

Fingerprint

Semiconductor materials
Acids
Cations
Ion exchange
Tunnels
Positive ions
Temperature

Keywords

  • Chalcogenides
  • Hydrothermal synthesis
  • Ion-exchange
  • Open-framework structures
  • Semiconductors

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{6849084d4c0a461eae08aeba63bfbe5b,
title = "Acid-induced conversions in open-framework semiconductors: From [Cd 4Sn3Se13]6- to [Cd 15Sn12Se46]14-, a remarkable disassembly/reassembly process",
abstract = "Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)",
keywords = "Chalcogenides, Hydrothermal synthesis, Ion-exchange, Open-framework structures, Semiconductors",
author = "Nan Ding and Kanatzidis, {Mercouri G}",
year = "2006",
month = "2",
day = "20",
doi = "10.1002/anie.200502787",
language = "English",
volume = "45",
pages = "1397--1401",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "9",

}

TY - JOUR

T1 - Acid-induced conversions in open-framework semiconductors

T2 - From [Cd 4Sn3Se13]6- to [Cd 15Sn12Se46]14-, a remarkable disassembly/reassembly process

AU - Ding, Nan

AU - Kanatzidis, Mercouri G

PY - 2006/2/20

Y1 - 2006/2/20

N2 - Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)

AB - Swapping structures and cations: In an acid-induced 3D-to-3D transformation at room temperature, K6Cd4Sn3Se13 is converted into K14-xHxCd15Sn 12Se46. The [Cd15Sn12Se 46]14- framework, which contains a tunnel network of accessible cages of labyrinthine complexity (see picture), is highly robust, acid resistant, and has excellent ion-exchange properties. (Figure Presented)

KW - Chalcogenides

KW - Hydrothermal synthesis

KW - Ion-exchange

KW - Open-framework structures

KW - Semiconductors

UR - http://www.scopus.com/inward/record.url?scp=33745938479&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33745938479&partnerID=8YFLogxK

U2 - 10.1002/anie.200502787

DO - 10.1002/anie.200502787

M3 - Article

VL - 45

SP - 1397

EP - 1401

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 9

ER -