Acrylate oligomer-based photopolymers for optical storage applications

M. L. Schilling, V. L. Colvin, L. Dhar, Alex Harris, F. C. Schilling, H. E. Katz, T. Wysocki, A. Hale, L. L. Blyler, C. Boyd

Research output: Contribution to journalArticle

86 Citations (Scopus)

Abstract

Photopolymers are attractive candidates for high-density holographic data storage because of their high sensitivity and refractive index contrast. We have incorporated several high-index organic monomers into high optical quality acrylate oligomer-based formulations. Using reactivity ratios, reaction kinetics, and component refractive indices as guidelines, a 6-fold increase in Δn has been achieved compared to an initial all-acrylate formulation. Samples prepared from these formulations have been used to write and read >200 high-quality holograms in a given volume of material. This is the first time a photopolymeric medium has successfully been used to multiplex this number of holograms. Using these resins, a protocol for the evaluation of photopolymers as holographic media has been developed.

Original languageEnglish
Pages (from-to)247-254
Number of pages8
JournalChemistry of Materials
Volume11
Issue number2
Publication statusPublished - 1999

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Photopolymers
Holograms
Oligomers
Refractive index
Reaction kinetics
Resins
Monomers
Data storage equipment
acrylic acid

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

Cite this

Schilling, M. L., Colvin, V. L., Dhar, L., Harris, A., Schilling, F. C., Katz, H. E., ... Boyd, C. (1999). Acrylate oligomer-based photopolymers for optical storage applications. Chemistry of Materials, 11(2), 247-254.

Acrylate oligomer-based photopolymers for optical storage applications. / Schilling, M. L.; Colvin, V. L.; Dhar, L.; Harris, Alex; Schilling, F. C.; Katz, H. E.; Wysocki, T.; Hale, A.; Blyler, L. L.; Boyd, C.

In: Chemistry of Materials, Vol. 11, No. 2, 1999, p. 247-254.

Research output: Contribution to journalArticle

Schilling, ML, Colvin, VL, Dhar, L, Harris, A, Schilling, FC, Katz, HE, Wysocki, T, Hale, A, Blyler, LL & Boyd, C 1999, 'Acrylate oligomer-based photopolymers for optical storage applications', Chemistry of Materials, vol. 11, no. 2, pp. 247-254.
Schilling ML, Colvin VL, Dhar L, Harris A, Schilling FC, Katz HE et al. Acrylate oligomer-based photopolymers for optical storage applications. Chemistry of Materials. 1999;11(2):247-254.
Schilling, M. L. ; Colvin, V. L. ; Dhar, L. ; Harris, Alex ; Schilling, F. C. ; Katz, H. E. ; Wysocki, T. ; Hale, A. ; Blyler, L. L. ; Boyd, C. / Acrylate oligomer-based photopolymers for optical storage applications. In: Chemistry of Materials. 1999 ; Vol. 11, No. 2. pp. 247-254.
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