Acrylate oligomer-based photopolymers for optical storage applications

M. L. Schilling, V. L. Colvin, L. Dhar, Alex Harris, F. C. Schilling, H. E. Katz, T. Wysocki, A. Hale, L. L. Blyler, C. Boyd

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87 Citations (Scopus)

Abstract

Photopolymers are attractive candidates for high-density holographic data storage because of their high sensitivity and refractive index contrast. We have incorporated several high-index organic monomers into high optical quality acrylate oligomer-based formulations. Using reactivity ratios, reaction kinetics, and component refractive indices as guidelines, a 6-fold increase in Δn has been achieved compared to an initial all-acrylate formulation. Samples prepared from these formulations have been used to write and read >200 high-quality holograms in a given volume of material. This is the first time a photopolymeric medium has successfully been used to multiplex this number of holograms. Using these resins, a protocol for the evaluation of photopolymers as holographic media has been developed.

Original languageEnglish
Pages (from-to)247-254
Number of pages8
JournalChemistry of Materials
Volume11
Issue number2
Publication statusPublished - 1999

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

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    Schilling, M. L., Colvin, V. L., Dhar, L., Harris, A., Schilling, F. C., Katz, H. E., Wysocki, T., Hale, A., Blyler, L. L., & Boyd, C. (1999). Acrylate oligomer-based photopolymers for optical storage applications. Chemistry of Materials, 11(2), 247-254.