Abstract
Reaction of Cp3AnCl complexes (Cp = η5- C5H5; An = Th, U) and (CH3C5H4)3ThCl with CpM(CO)2Na (M = Fe, Ru) yields the corresponding metal-metal bonded compounds Cp3An-M(Cp)(CO)2 and (CH3C5H4)3Th-M(Cp)(CO)2. Electron-releasing tendencies follow the order Cp3U- > Cp3Th- ≫ [(CH3)5C5]2Th(X)-(X = Cl, I, CH3). Evidence for hindered rotation about the metal-metal bonds and facile cleavage by alcohols and ketones is presented.
| Original language | English |
|---|---|
| Pages (from-to) | 2621-2623 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 6 |
| Issue number | 12 |
| Publication status | Published - 1987 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Actinide-to-transition metal bonds. Synthesis, characterization, and properties of metal-metal bonded systems having the tris(cyclopentadienyl)actinide fragment. / Sternal, Richard S.; Marks, Tobin J.
In: Organometallics, Vol. 6, No. 12, 1987, p. 2621-2623.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Actinide-to-transition metal bonds. Synthesis, characterization, and properties of metal-metal bonded systems having the tris(cyclopentadienyl)actinide fragment
AU - Sternal, Richard S.
AU - Marks, Tobin J
PY - 1987
Y1 - 1987
N2 - Reaction of Cp3AnCl complexes (Cp = η5- C5H5; An = Th, U) and (CH3C5H4)3ThCl with CpM(CO)2Na (M = Fe, Ru) yields the corresponding metal-metal bonded compounds Cp3An-M(Cp)(CO)2 and (CH3C5H4)3Th-M(Cp)(CO)2. Electron-releasing tendencies follow the order Cp3U- > Cp3Th- ≫ [(CH3)5C5]2Th(X)-(X = Cl, I, CH3). Evidence for hindered rotation about the metal-metal bonds and facile cleavage by alcohols and ketones is presented.
AB - Reaction of Cp3AnCl complexes (Cp = η5- C5H5; An = Th, U) and (CH3C5H4)3ThCl with CpM(CO)2Na (M = Fe, Ru) yields the corresponding metal-metal bonded compounds Cp3An-M(Cp)(CO)2 and (CH3C5H4)3Th-M(Cp)(CO)2. Electron-releasing tendencies follow the order Cp3U- > Cp3Th- ≫ [(CH3)5C5]2Th(X)-(X = Cl, I, CH3). Evidence for hindered rotation about the metal-metal bonds and facile cleavage by alcohols and ketones is presented.
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UR - http://www.scopus.com/inward/citedby.url?scp=0000315818&partnerID=8YFLogxK
M3 - Article
VL - 6
SP - 2621
EP - 2623
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 12
ER -