Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3) 3Cl2(CH2PMe3)]Cl·CH 2Cl2 and trans-[Rh(Me2PCH2CH 2PMe2)2Cl(CH2Cl)]Cl

Todd B. Marder, William C. Fultz, Joseph C. Calabrese, Richard L. Harlow, David Milstein

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Abstract

Sixteen-electron RhI complexes of basic phosphines react with CH2Cl2 yielding either RhCH2Cl or RhCH 2PMe3 complexes; an example of each has been structurally characterized.

Original languageEnglish
Pages (from-to)1543-1545
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number20
DOIs
Publication statusPublished - 1987

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phosphine
Phosphines
Iridium
Rhodium
Methylene Chloride
Dichloromethane
Chemical activation
Electrons

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3) 3Cl2(CH2PMe3)]Cl·CH 2Cl2 and trans-[Rh(Me2PCH2CH 2PMe2)2Cl(CH2Cl)]Cl",
abstract = "Sixteen-electron RhI complexes of basic phosphines react with CH2Cl2 yielding either RhCH2Cl or RhCH 2PMe3 complexes; an example of each has been structurally characterized.",
author = "Marder, {Todd B.} and Fultz, {William C.} and Calabrese, {Joseph C.} and Harlow, {Richard L.} and David Milstein",
year = "1987",
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language = "English",
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journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
number = "20",

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AU - Marder, Todd B.

AU - Fultz, William C.

AU - Calabrese, Joseph C.

AU - Harlow, Richard L.

AU - Milstein, David

PY - 1987

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AB - Sixteen-electron RhI complexes of basic phosphines react with CH2Cl2 yielding either RhCH2Cl or RhCH 2PMe3 complexes; an example of each has been structurally characterized.

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