Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

Simon B. Duckett; Richard Eisenberg; Alan S Goldman

doi:10.1039/C39930001185

Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO)

Simon B. Duckett, Richard Eisenberg, Alan S Goldman

Rutgers University

Research output: Contribution to journal › Article

31 Citations (Scopus)

Abstract

The oxidative addition of H₂ to [RhCl(CO)(PMe₃) ₂] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

Original language	English
Pages (from-to)	1185-1187
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39930001185
Publication status	Published - 1993

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ASJC Scopus subject areas

Molecular Medicine

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Duckett, S. B., Eisenberg, R., & Goldman, A. S. (1993). Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO). Journal of the Chemical Society, Chemical Communications, (15), 1185-1187. https://doi.org/10.1039/C39930001185

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Access to Document

10.1039/C39930001185