Abstract
The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.
| Original language | English |
|---|---|
| Pages (from-to) | 1185-1187 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 1993 |
ASJC Scopus subject areas
- Molecular Medicine
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Duckett, S. B., Eisenberg, R., & Goldman, A. S. (1993). Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO). Journal of the Chemical Society, Chemical Communications, (15), 1185-1187. https://doi.org/10.1039/C39930001185