Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

Simon B. Duckett; Richard Eisenberg; Alan S Goldman

doi:10.1039/C39930001185

Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO)

Simon B. Duckett, Richard Eisenberg, Alan S Goldman

Rutgers University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The oxidative addition of H₂ to [RhCl(CO)(PMe₃) ₂] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

Original language	English
Pages (from-to)	1185-1187
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	15
DOIs	https://doi.org/10.1039/C39930001185
Publication status	Published - 1993

ASJC Scopus subject areas

Molecular Medicine

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Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO). / Duckett, Simon B.; Eisenberg, Richard; Goldman, Alan S.

In: Journal of the Chemical Society, Chemical Communications, No. 15, 1993, p. 1185-1187.

Research output: Contribution to journal › Article › peer-review

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title = "Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)",

abstract = "The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.",

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AU - Eisenberg, Richard

AU - Goldman, Alan S

PY - 1993

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N2 - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

AB - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

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Activation of H₂ by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe ₃)₂(μ-H)(μ-Cl)RH(PMe₃)(CO)

Abstract

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