Abstract
The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.
| Original language | English |
|---|---|
| Pages (from-to) | 1185-1187 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 1993 |
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ASJC Scopus subject areas
- Molecular Medicine
Cite this
Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO). / Duckett, Simon B.; Eisenberg, Richard; Goldman, Alan S.
In: Journal of the Chemical Society, Chemical Communications, No. 15, 1993, p. 1185-1187.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)
AU - Duckett, Simon B.
AU - Eisenberg, Richard
AU - Goldman, Alan S
PY - 1993
Y1 - 1993
N2 - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.
AB - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.
UR - http://www.scopus.com/inward/record.url?scp=37049072437&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049072437&partnerID=8YFLogxK
U2 - 10.1039/C39930001185
DO - 10.1039/C39930001185
M3 - Article
SP - 1185
EP - 1187
JO - Chemical Communications
JF - Chemical Communications
SN - 1359-7345
IS - 15
ER -