Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

Simon B. Duckett, Richard Eisenberg, Alan S Goldman

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

Original languageEnglish
Pages (from-to)1185-1187
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number15
DOIs
Publication statusPublished - 1993

Fingerprint

Rhodium
Carbon Monoxide
Nuclear magnetic resonance spectroscopy
Chemical activation
Hydrogen
Magnetic Resonance Spectroscopy

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

@article{8ff5a963359c44b0ad5768785310fd10,
title = "Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)",
abstract = "The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.",
author = "Duckett, {Simon B.} and Richard Eisenberg and Goldman, {Alan S}",
year = "1993",
doi = "10.1039/C39930001185",
language = "English",
pages = "1185--1187",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry",
number = "15",

}

TY - JOUR

T1 - Activation of H2 by chlorocarbonylbis(trimethylphosphine) rhodium(I) labilizes CO and produces the new binuclear complex H(Cl)Rh(PMe 3)2(μ-H)(μ-Cl)RH(PMe3)(CO)

AU - Duckett, Simon B.

AU - Eisenberg, Richard

AU - Goldman, Alan S

PY - 1993

Y1 - 1993

N2 - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

AB - The oxidative addition of H2 to [RhCl(CO)(PMe3) 2] is followed using NMR spectroscopy in conjunction with para-enriched hydrogen and leads to CO labilization and formation of an unusual binuclear complex.

UR - http://www.scopus.com/inward/record.url?scp=37049072437&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=37049072437&partnerID=8YFLogxK

U2 - 10.1039/C39930001185

DO - 10.1039/C39930001185

M3 - Article

SP - 1185

EP - 1187

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 15

ER -