Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2MO10O40]5- polyoxometalate ion

Revital Ben-Daniel, Ronny Neumann

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

Original languageEnglish
Pages (from-to)92-95
Number of pages4
JournalAngewandte Chemie - International Edition
Volume42
Issue number1
DOIs
Publication statusPublished - Jan 3 2003

Fingerprint

Vanadium
Catalytic oxidation
Nitrous Oxide
Ketones
Aldehydes
Alcohols
Chemical activation
Ions
Oxidation
Oxides
Substrates
polyoxometalate I

Keywords

  • Alcohols
  • Homogeneous catalysis
  • Nitrogen oxides
  • Oxidation
  • Polyoxometalates

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

@article{4a0ce942a244428a8b3f44fb375bb9f9,
title = "Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2MO10O40]5- polyoxometalate ion",
abstract = "A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).",
keywords = "Alcohols, Homogeneous catalysis, Nitrogen oxides, Oxidation, Polyoxometalates",
author = "Revital Ben-Daniel and Ronny Neumann",
year = "2003",
month = "1",
day = "3",
doi = "10.1002/anie.200390062",
language = "English",
volume = "42",
pages = "92--95",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "1",

}

TY - JOUR

T1 - Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2MO10O40]5- polyoxometalate ion

AU - Ben-Daniel, Revital

AU - Neumann, Ronny

PY - 2003/1/3

Y1 - 2003/1/3

N2 - A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

AB - A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

KW - Alcohols

KW - Homogeneous catalysis

KW - Nitrogen oxides

KW - Oxidation

KW - Polyoxometalates

UR - http://www.scopus.com/inward/record.url?scp=0037414949&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037414949&partnerID=8YFLogxK

U2 - 10.1002/anie.200390062

DO - 10.1002/anie.200390062

M3 - Article

VL - 42

SP - 92

EP - 95

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 1

ER -