Activation of nitrous oxide and selective oxidation of alcohols and alkylarenes catalyzed by the [PV2MO10O40]5- polyoxometalate ion

Revital Ben-Daniel, Ronny Neumann

Research output: Contribution to journalArticle

67 Citations (Scopus)

Abstract

A vanadium-substituted polyoxomolybdate ion ([PV2Mo10O40]5-, top right) can activate nitrous oxide to promote the highly selective catalytic oxidation of primary and secondary alcohols to aldehydes and ketones, and the oxidation of various alkylaromatic substrates (see scheme).

Original languageEnglish
Pages (from-to)92-95
Number of pages4
JournalAngewandte Chemie - International Edition
Volume42
Issue number1
DOIs
Publication statusPublished - Jan 3 2003

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Keywords

  • Alcohols
  • Homogeneous catalysis
  • Nitrogen oxides
  • Oxidation
  • Polyoxometalates

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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